Herbicidal mixtures comprising l-glufosinate and their use in corn cultures

ABSTRACT

The present invention relates to herbicidal mixtures and their methods and uses for controlling undesirable vegetation in glufosinate-tolerant corn, wherein the herbicidal mixtures comprise L-glufosinate and and at least one herbicidal compound II selected from clethodim, cycloxydim, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, quizalofop, quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, chlorimuron, chlorimuron-ethyl, foramsulfuron, halosulfuron, halosulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron, rimsulfuron, thifensulfuron, thifensulfuron-methyl, tritosulfuron, imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr isopropylammonium, imazethapyr, imazethapyr ammonium, diclosulam, flumetsulam, florasulam, metosulam, thiencarbazone, thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil and its salts and esters, bentazone, bentazone-sodium, pyridate, carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl, flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone, tiafenacil, trifludimoxazin, picolinafen, bicyclopyrone, clomazone, isoxaflutole, mesotrione, sulcotrione, tembotrione, tolpyralate, topramezone, fenquinotrione, glyphosate, glyphosate dimethylammmonium, glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium (sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid, dimethenamid-P, metazachlor, metolachlor, S-metolachlor, pethoxamid, flufenacet, pyroxasulfone, 2,4-D and its salts and esters, clopyralid and its salts and esters, dicamba and its salts and esters, quinclorac, quinclorac dimethylammonium, quinmerac,diflufenzopyr, diflufenzopyr-sodium, cinmethylin, MCPA and its salts and esters and other compounds.

The present invention relates to herbicidal mixture comprisingL-glufosinate and and a herbicidal compound II selected from clethodim,cycloxydim, haloxyfop, haloxyfop-methyl, haloxyfop-P,haloxyfop-P-methyl, quizalofop, quizalofop-ethyl, quizalofop-tefuryl,quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, chlorimuron,chlorimuron-ethyl, foramsulfuron, halosulfuron, halosulfuron-methyl,iodosulfuron, iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron,rimsulfuron, thifensulfuron, thifensulfuron-methyl, tritosulfuron,imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr,imazapyr isopropylammonium, imazethapyr, imazethapyr ammonium,diclosulam, flumetsulam, florasulam, metosulam, thiencarbazone,thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil andits salts and esters, bentazone, bentazone-sodium, pyridate,carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, picolinafen, bicyclopyrone, clomazone,isoxaflutole, mesotrione, sulcotrione, tembotrione, tolpyralate,topramezone, fenquinotrione, glyphosate, glyphosate dimethylammmonium,glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metazachlor, metolachlor, S-metolachlor, pethoxamid,flufenacet, pyroxasulfone, 2,4-D and its salts and esters, clopyralidand its salts and esters, dicamba and its salts and esters, quinclorac,quinclorac dimethylammonium, quinmerac, diflufenzopyr,diflufenzopyr-sodium, cinmethylin, MCPA and its salts and esters, II-83:ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate(CAS 353292-31-6, S-3100), II-84:2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-aceticacid methyl ester (CAS 1970221-16-9), II-85:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide(CAS 2158276-22-1), II-86:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid ethyl ester (CAS 2158274-56-5), II-87:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide(CAS 2158274-53-2), II-88:2-[-2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid ethyl ester (CAS 2158274-50-9), II-89: ethyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate(CAS 2230679-62-4), II-90:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid methyl ester (CAS 2158275-73-9), II-91:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid methyl ester (CAS 2158274-96-3) and II-92: methyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate.

The invention also relates to methods and uses for controllingundesirable vegetation in glufosinate-tolerant corn.

Tolerant or resistant corn varieties (e.g. transgenic corn varieties)provide the option to use herbicides, which are originally not selectivein respective tolerant or resistant corn in addition to conventionalweed control system. One example is glufosinate, which can not only beused for pre-plant burn-down both in conventional corn and corn that istolerant against herbicides including glufosinate; but which can alsoachieve effective weed control by post-emergence application inglufosinate tolerant corn. Glufosinate is a broad-spectrum herbicidethat controls most grass and broadleaf herbicide species; however, thereare a few tough to control species or resistant biotypes that it doesnot fully control. Another challenge is the duration of action, or thedegradation rate of the herbicide. Furthermore, changes in thesensitivity of harmful plants, which may occur upon prolonged use of theherbicides or within a geographical limited area, must also be takeninto consideration. The resulting loss of action against individualplants can sometimes compensated for to a certain extent by higherapplication rates of the herbicides. However, there is always a demandfor methods to achieve the herbicidal effect with lower applicationrates of active compounds to reduce not only the amount of an activecompound required for application, but also the amount of formulationauxiliaries. Thus, low application rates are for economic andenvironmental reasons an object eco-friendliness of the herbicidetreatment.

One possibility for improving the use profile of a herbicide is thecombination of the herbicide in question with one or more other activecompounds which have the desired additional properties. However, thecombined use of a plurality of active compounds may lead to phenomena ofa chemical, physical and biological incompatibility (e.g. instability ofa coformulation, decomposition of an active compound or antagonism inthe biological action of the active compounds). Thus, finding effectiveglufosinate combinations with an additional herbicide faces thechallenge that in many instances the effectiveness of such combinationsis not satisfactory and high application rates are still required toachieve an acceptable weed control.

Thus, it is an object of the present invention to find combinations ofactive compounds with a favorable profile of action, high stability and,ideally, synergistically enhanced activity for application inglufosinate tolerant corn, which allows the application rate to bereduced in comparison with solutions provided by prior art mixtures.Moreover, the persistence of the herbicidal activity of the mixtureshould be sufficiently long in order to achieve control of the weedsover a sufficient long time period thus allowing a more flexibleapplication. The mixtures should also show an accelerated action onharmful plants and not affect the growth of the corn plant.

Glufosinate is a racemate of two enantiomers, out of which only oneshows sufficient herbicidal activity (see e.g. U.S. Pat. No. 4,265,654and JP92448/83). Even though various methods to prepare L-glufosinate(and respective salts) are known, the mixtures known in the art do notpoint at the stereochemistry, meaning that the racemate is present (e.g.WO 2003024221, WO2009141367, WO2013154396, DE 19815820).

Surprisingly, it has been found that mixtures of L-glufosinate or itssalt and the herbicidal compound II show enhanced herbicide actionagainst undesirable vegetation in pre-plant burn-down prior to plantingof conventional corn and corn that is tolerant against herbicidesincluding glufosinate and in post-emergence use in glufosinate tolerantcorn and/or show superior compatibility with corn, i.e. their use leadsto a reduced damage of the corn plants and/or does not result inincreased damage of the corn plants, if compared to mixtures of racemicglufosinate and the herbicidal compound II, or if compared toL-glufosinate or its salts alone.

Thus, the present invention relates to herbicidal mixtures of

-   -   1) L-glufosinate or its salt as compound I and    -   2) at least one herbicidal compound II selected from clethodim,        cycloxydim, haloxyfop, haloxyfop-methyl, haloxyfop-P,        haloxyfop-P-methyl, quizalofop, quizalofop-ethyl,        quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl,        quizalofop-P-tefuryl, chlorimuron, chlorimuron-ethyl,        foramsulfuron, halosulfuron, halosulfuron-methyl, iodosulfuron,        iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron,        rimsulfuron, thifensulfuron, thifensulfuron-methyl,        tritosulfuron, imazamox, imazamox ammonium, imazapic, imazapic        ammonium, imazapyr, imazapyr iso-propylammonium, imazethapyr,        imazethapyr ammonium, diclosulam, flumetsulam, florasulam,        metosulam, thiencarbazone, thiencarbazone-methyl, atrazine,        simazine, terbuthylazin, bromoxynil and its salts and esters,        bentazone, bentazone-sodium, pyridate, carfentrazone,        carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,        flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil,        sulfentrazone, tiafenacil, trifludimoxazin, picolinafen,        bicyclopyrone, clomazone, isoxaflutole, mesotrione, sulcotrione,        tembotrione, tolpyralate, topramezone, fenquinotrione,        glyphosate, glyphosate-isopropylammonium, glyphosate-potassium,        glyphosate-trimesium (sulfosate), pendimethalin, acetochlor,        butachlor, dimethenamid, dimethenamid-P, metazachlor,        metolachlor, S-metolachlor, pethoxamid, flufenacet,        pyroxasulfone, 2,4-D and its salts and esters, clopyralid and        its salts and esters, dicamba and its salts and esters,        quinclorac, quinclorac dimethylammonium,        quinmerac,diflufenzopyr, diflufenzopyr-sodium, cinmethylin. MCPA        and its salts and esters, II-83: ethyl        [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate        (CAS 353292-31-6, S-3100), II-84:        2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-acetic        acid methyl ester (CAS 1970221-16-9), II-85:        2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide        (CAS 2158276-22-1), II-86:        2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-acetic        acid ethyl ester (CAS 2158274-56-5), II-87:        2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide        (CAS 2158274-53-2), II-88:        2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-acetic        acid ethyl ester (CAS 2158274-50-9), II-89: ethyl        2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate        (CAS 2230679-62-4), II-90:        2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-acetic        acid methyl ester (CAS 2158275-73-9), II-91:        2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-acetic        acid methyl ester (CAS 2158274-96-3) and II-92: methyl        2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate.

Glufosinate [common name ofDL-4-[hydroxyl(methyl)phosphinoyl]-DL-homoalaninate] and its salts suchas glufosinate ammonium and its herbicidal acitivity have been describede.g. by F. Schwerdtle et al. Z. Pflanzenkr. Pflanzenschutz, 1981,Sonderheft IX, pp. 431-440. Racemic glufosinate and its salts arecommercially available, e.g. from Bayer CropScience under the tradenamesBasta™ and Liberty™.

L-Glufosinate, also called glufosinate-P, is(2S)-2-amino-4-[hydroxy(methyl)phosphinoyl]butyric acid (CAS Reg. No.35597-44-5). Relevant salts of L-glufosinate are L-glufosinate-ammonium(also called glufosinate-P-ammonium), which is ammonium(2S)-2-amino-4-(methylphosphinato)butyric acid (CAS Reg. No.73777-50-1); L-glufosinate-sodium (also called glufosinate-P-sodium),which is sodium (2S)-2-amino-4-(methylphosphinato)butyric acid (CAS Reg.No. 70033-13-5) and L-glufosinate-potassium (also calledglufosinate-P-potassium), which is potassium(2S)-2-amino-4-(methylphosphinato)butyric acid.

L-Glufosinate as used in the present invention comprises more than 70%by weight of the L-enantiomer; preferably more than 80% by weight of theL-enantiomer; more preferably more than 90% of the L-enantiomer, mostpreferably more than 95% of the L-enantiomer and can be prepared asreferred to above.

In a preferred embodiment, the abovementioned invention relates toherbicidal mixtures as described above, wherein L-glufosinate comprisesmore than 70% by weight of the L-enantiomer.

L-glufosinate can be prepared according to methods known in the art,e.g. as described in WO2006/104120, U.S. Pat. No. 5,530,142, EP0127429and J. Chem. Soc. Perkin Trans. 1, 1992, 1525-1529.

Compounds II as well as their pesticidal action and methods forproducing them are generally known, for example in the Pesticide ManualV5.2 (ISBN 978 1 901396 85 0) (2008-2011) amongst other sources.Compound II-83 is known from EP 1122244. Compound II-84 is known fromWO2016/120116. Compounds II-85, II-86, II-87, II-88, II-90 and II-91 areknown from WO2017/202768. Compounds II-89 and II-92 are known fromWO2018/108695.

In the inventive mixtures the weight ratio of compound I to compound IIis preferably from 1000:1 to 1:500, 400:1 to 1:40, more preferably 500:1to 1:250, in particular from 200:1 to 1:20, even more preferably from100:1 to 1:10, most preferably 50:1 to 1:5.

Furthermore, mixtures are preferred, which containL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid. Especially preferred are mixtures, whichcontain L-glufosinate-ammonium as L-glufosinate salt.

In one embodiment, the present present invention relates to herbicidalmixtures of

-   -   1) L-glufosinate or its salt as compound I and    -   2) a herbicidal compound II selected from clethodim, cycloxydim,        haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl,        quizalofop, quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P,        quizalofop-P-ethyl, quizalofop-P-tefuryl, chlorimuron,        chlorimuron-ethyl, foramsulfuron, halosulfuron,        halosulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium,        nicosulfuron, prosulfuron, rimsulfuron, thifensulfuron,        thifensulfuron-methyl, tritosulfuron, imazamox, imazapic,        imazapyr, imazethapyr, diclosulam, flumetsulam, florasulam,        metosulam, thiencarbazone, thiencarbazone-methyl, atrazine,        simazine, terbuthylazin, bromoxynil and its salts and esters,        bentazone, bentazone-sodium, pyridate, carfentrazone,        carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,        flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil,        trifludimoxazin, picolinafen, bicyclopyrone, clomazone,        isoxaflutole, mesotrione, sulcotrione, tembotrione, tolpyralate,        topramezone, fenquinotrione, glyphosate,        glyphosate-isopropylammonium, glyphosate-potassium,        glyphosate-trimesium (sulfosate), pendimethalin, acetochlor,        butachlor, dimethenamid, dimethenamid-P, metazachlor,        metolachlor, S-metolachlor, pethoxamid, flufenacet,        pyroxasulfone, 2,4-D and its salts and esters, clopyralid and        its salts and esters, dicamba and its salts and esters,        quinclorac, quinmerac, diflufenzopyr, diflufenzopyr-sodium,        cinmethylin and MCPA and its salts and esters.

Preferred compounds II are clethodim, cycloxydim, haloxyfop,haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, quizalofop,quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl,quizalofop-P-tefuryl, chlorimuron, chlorimuron-ethyl, foramsulfuron,halosulfuron, halosulfuron-methyl, iodosulfuron,iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron, rimsulfuron,thifensulfuron, thifensulfuron-methyl, tritosulfuron, imazamox, imazamoxammonium, imazapic, imazapic ammonium, imazapyr, imazapyrisopropylammonium, imazethapyr, imazethapyr ammonium, diclosulam,flumetsulam, florasulam, metosulam, thiencarbazone,thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil andits salts and esters, bentazone, bentazone-sodium, pyridate,carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, bicyclopyrone, clomazone, isoxaflutole,mesotrione, sulcotrione, tembotrione, tolpyralate, topramezone,fenquinotrione, glyphosate, glyphosate dimethylammmonium,glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metolachlor, S-metolachlor, pethoxamid, flufenacet,pyroxasulfone, 2,4-D and its salts and esters, clopyralid and its saltsand esters, dicamba and its salts and esters, diflufenzopyr,diflufenzopyr-sodium, MCPA and its salts and esters, II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate(CAS 353292-31-6, S-3100), II-84:2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-aceticacid methyl ester (CAS 1970221-16-9), II-85:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide(CAS 2158276-22-1), II-86:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid ethyl ester (CAS 2158274-56-5), II-87:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide(CAS 2158274-53-2), II-88:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid ethyl ester (CAS 2158274-50-9), II-89: ethyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate(CAS 2230679-62-4), II-90:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid methyl ester (CAS 2158275-73-9), II-91:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid methyl ester (CAS 2158274-96-3) and II-92: methyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate.

Thus, preferred mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II selected fromthe group consisting of clethodim, cycloxydim, haloxyfop,haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, quizalofop,quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl,quizalofop-P-tefuryl, chlorimuron, chlorimuron-ethyl, foramsulfuron,halosulfuron, halosulfuron-methyl, iodosulfuron,iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron, rimsulfuron,thifensulfuron, thifensulfuron-methyl, tritosulfuron, imazamox, imazamoxammonium, imazapic, imazapic ammonium, imazapyr, imazapyrisopropylammonium, imazethapyr, imazethapyr ammonium, diclosulam,flumetsulam, florasulam, metosulam, thiencarbazone,thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil andits salts and esters, bentazone, bentazone-sodium, pyridate,carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, bicyclopyrone, clomazone, isoxaflutole,mesotrione, sulcotrione, tembotrione, tolpyralate, topramezone,fenquinotrione, glyphosate, glyphosate dimethylammonium,glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metolachlor, S-metolachlor, pethoxamid, flufenacet,pyroxasulfone, 2,4-D and its salts and esters, clopyralid and its saltsand esters, dicamba and its salts and esters, diflufenzopyr,diflufenzopyr-sodium, MCPA and its salts and esters, compounds II-83,II-84, II-85, II-86, II-87, II-88, II-89, II-90, II-91 and II-92.

Preferred mixtures of the present invention are mixtures ofL-glufosinate-or a salt thereof and a herbicidal compound II selectedfrom the group consisting of saflufenacil, sulfentrazone, tiafenacil,trifludimoxazin, and compounds II-83, II-84, II-85, II-86, II-87, II-88,II-89, II-90, II-91 and II-92;

bicyclopyrone, tolpyralate;

dimethenamid, dimethenamid-P, metolachlor, S-metolachlor, pethoxamid,pyroxasulfone;

2,4-D and its salts and esters, dicamba and its salts and esters;

diflufenzopyr, diflufenzopyr sodium.

Most preferred mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II selected fromthe group consisting of saflufenacil, sulfentrazone, tiafenacil,trifludimoxazin, and compounds II-83, II-84, II-85, II-86, II-87, II-88,II-89, II-90, II-91 and II-92;

bicyclopyrone, tolpyralate;

dimethenamid, dimethenamid-P, metolachlor, S-metolachlor, pethoxamid,pyroxasulfone;

2,4-D and its salts and esters, dicamba and its salts and esters;

diflufenzopyr, diflufenzopyr sodium.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-or a salt thereof and a herbicidal compound II selectedfrom the group consisting of saflufenacil, sulfentrazone, tiafenacil,trifludimoxazin, and compounds II-83, II-84, II-85, II-86, II-87, II-88and II-89; preferably selected from the group of compounds saflufenacil,trifludimoxazin, II-83, II-84, II-85, II-86, II-87, II-88, II-89, II-90,II-91 and II-92.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-or a salt thereof and a herbicidal compound II selectedfrom the group of bicyclopyrone and tolpyralate.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-or a salt thereof and a herbicidal compound II selectedfrom the group of dimethenamid, dimethenamid-P, metolachlor,S-metolachlor, pethoxamid and pyroxasulfone.

In one embodiment, the mixtures of the present invention are mixturesL-glufosinate-or a salt thereof and a herbicidal compound II selectedfrom the group of 2,4-D and its salts and esters anddicamba and itssalts and esters.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-or a salt thereof and a herbicidal compound II which isdiflufenzopyr or diflufenzopyr sodium.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II selected fromthe group consisting of saflufenacil, sulfentrazone, tiafenacil,trifludimoxazin, and compounds II-83, II-84, II-85, II-86, II-87, II-88,II-89, II-90, II-91 and II-92;

preferably selected from the group of compounds saflufenacil,trifludimoxazin, II-83, II-84, II-85, II-86, II-87, II-88, II-89, II-90,II-91 and II-92.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II selected fromthe group of bicyclopyrone and tolpyralate.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II selected fromthe group of dimethenamid, dimethenamid-P, metolachlor, S-metolachlor,pethoxamid and pyroxasulfone.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II selected fromthe group of 2,4-D and its salts and esters and dicamba and its saltsand esters.

In one embodiment, the mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and a herbicidal compound II which isdiflufenzopyr or diflufenzopyr sodium.

All preferred mixtuers are listed in table 2, wherein the followingabbreviations are used in table 1:

TABLE 1 Compound Abbreviation L-glufosinate-ammonium  I-1L-glufosinate-sodium  I-2 L-glufosinate as free acid  I-3 clethodim II-1cycloxydim II-2 haloxyfop II-3 haloxyfop-methyl II-4 haloxyfop-P II-5haloxyfop-P-methyl II-6 quizalofop II-7 quizalofop-ethyl II-8quizalofop-tefuryl II-9 quizalofop-P II-10 quizalofop-P-ethyl II-11quizalofop-P-tefuryl II-12 foramsulfuron II-13 halosulfuron II-14halosulfuron-methyl II-15 iodosulfuron II-16 iodosulfuron-methyl-sodiumII-17 nicosulfuron II-18 rimsulfuron II-19 thifensulfuron II-20thifensulfuron-methyl II-21 tritosulfuron II-22 imazamox II-23 imazamoxammonium II-23a imazapic II-24 imazapic ammonium, II-24a imazapyr II-25imazapyr isopropylammonium II-25a imazethapyr II-26 imazethapyrammonium, II-26a thiencarbazone II-27 thiencarbazone-methyl II-28atrazine II-29 terbuthylazin II-30 bromoxynil and its salts and estersII-31 bentazone II-32 bentazone-sodium II-33 flumioxazin II-34saflufenacil II-35 trifludimoxazin II-36 bicyclopyrone II-37isoxaflutole II-38 mesotrione II-39 sulcotrione II-40 tembotrione II-41tolpyralate II-42 topramezone II-43 fenquinotrione II-44 glyphosateII-45 glyphosate dimethylammmonium, II-45a glyphosate-isopropylammoniumII-46 glyphosate-potassium II-47 glyphosate-trimesium (sulfosate) II-48pendimethalin II-49 acetochlor II-50 butachlor II-51 dimethenamid II-52dimethen-amid-P II-53 metolachlor II-54 S-metolachlor II-55 flufenacetII-56 pyroxasulfone II-57 2,4-D and its salts and esters II-58clopyralid and its salts and esters II-59 dicamba and its salts andesters II-60 diflufenzopyr II-61 diflufenzopyr-sodium II-62 MCPA and itssalts and esters II-63 chlorimuron II-64 chlorimuron-ethyl II-65prosul-furon II-66 diclosulam II-67 flumetsulam II-68 florasulam II-69metosulam II-70 simazine II-71 pyridate II-72 carfentrazone II-73carfentrazone-ethyl II-74 flumiclorac II-75 flumiclorac-pentyl II-76fluthiacet II-77 fluthiacet-methyl II-78 clomazone II-79 pethoxamidII-80 suflentrazone II-81 tiafenacil II-82 see below II-83 see belowII-84 see below II-85 see below II-86 see below II-87 see below II-88see below II-89 see below II-90 see below II-91 see below II-92quinclorac II-93 quinclorac dimethylammonium II-93a

-   -   II-83: ethyl        [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate        (CAS 353292-31-6; S-3100).    -   II-84:        2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-acetic        acid methyl ester (CAS 1970221-16-9)    -   II-85:        2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide        (CAS 2158276-22-1)    -   II-86:        2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-acetic        acid ethyl ester (CAS 2158274-56-5)    -   II-87:        2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide        (CAS 2158274-53-2)    -   II-88:        2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-acetic        acid ethyl ester (CAS 2158274-50-9)    -   II-89: ethyl        2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluorophenoxy]-2-pyridyl]oxy]acetate        (CAS 2230679-62-4)    -   II-90:        2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-acetic        acid methyl ester (CAS 2158275-73-9)    -   II-91:        2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-acetic        acid methyl ester (CAS 2158274-96-3)

-   II-92: methyl    2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluorophenoxy]-2-pyridyl]oxy]acetate

TABLE 2 No I II M-1 I-1 II-1 M-2 I-1 II-2 M-3 I-1 II-3 M-4 I-1 II-4 M-5I-1 II-5 M-6 I-1 II-6 M-7 I-1 II-7 M-8 I-1 II-8 M-9 I-1 II-9 M-10 I-1II-10 M-11 I-1 II-11 M-12 I-1 II-12 M-13 I-1 II-13 M-14 I-1 II-14 M-15I-1 II-15 M-16 I-1 II-16 M-17 I-1 II-17 M-18 I-1 II-18 M-19 I-1 II-19M-20 I-1 II-20 M-21 I-1 II-21 M-22 I-1 II-22 M-23 I-1 II-23 M-24 I-1II-24 M-25 I-1 II-25 M-26 I-1 II-26 M-27 I-1 II-27 M-28 I-1 II-28 M-29I-1 II-29 M-30 I-1 II-30 M-31 I-1 II-31 M-32 I-1 II-32 M-33 I-1 II-33M-34 I-1 II-34 M-35 I-1 II-35 M-36 I-1 II-36 M-37 I-1 II-37 M-38 I-1II-38 M-39 I-1 II-39 M-40 I-1 II-40 M-41 I-1 II-41 M-42 I-1 II-42 M-43I-1 II-43 M-44 I-1 II-44 M-45 I-1 II-45 M-46 I-1 II-46 M-47 I-1 II-47M-48 I-1 II-48 M-49 I-1 II-49 M-50 I-1 II-50 M-51 I-1 II-51 M-52 I-1II-52 M-53 I-1 II-53 M-54 I-1 II-54 M-55 I-1 II-55 M-56 I-1 II-56 M-57I-1 II-57 M-58 I-1 II-58 M-59 I-1 II-59 M-60 I-1 II-60 M-61 I-1 II-61M-62 I-1 II-62 M-63 I-1 II-63 M-64 I-1 II-64 M-65 I-1 II-65 M-66 I-1II-66 M-67 I-1 II-67 M-68 I-1 II-68 M-69 I-1 II-69 M-70 I-1 II-70 M-71I-1 II-71 M-72 I-1 II-72 M-73 I-1 II-73 M-74 I-1 II-74 M-75 I-1 II-75M-76 I-1 II-76 M-77 I-1 II-77 M-78 I-1 II-78 M-79 I-1 II-79 M-80 I-1II-80 M-81 I-2 II-1 M-82 I-2 II-2 M-83 I-2 II-3 M-84 I-2 II-4 M-85 I-2II-5 M-86 I-2 II-6 M-87 I-2 II-7 M-88 I-2 II-8 M-89 I-2 II-9 M-90 I-2II-10 M-91 I-2 II-11 M-92 I-2 II-12 M-93 I-2 II-13 M-94 I-2 II-14 M-95I-2 II-15 M-96 I-2 II-16 M-97 I-2 II-17 M-98 I-2 II-18 M-99 I-2 II-19M-100 I-2 II-20 M-101 I-2 II-21 M-102 I-2 II-22 M-103 I-2 II-23 M-104I-2 II-24 M-105 I-2 II-25 M-106 I-2 II-26 M-107 I-2 II-27 M-108 I-2II-28 M-109 I-2 II-29 M-110 I-2 II-30 M-111 I-2 II-31 M-112 I-2 II-32M-113 I-2 II-33 M-114 I-2 II-34 M-115 I-2 II-35 M-116 I-2 II-36 M-117I-2 II-37 M-118 I-2 II-38 M-119 I-2 II-39 M-120 I-2 II-40 M-121 I-2II-41 M-122 I-2 II-42 M-123 I-2 II-43 M-124 I-2 II-44 M-125 I-2 II-45M-126 I-2 II-46 M-127 I-2 II-47 M-128 I-2 II-48 M-129 I-2 II-49 M-130I-2 II-50 M-131 I-2 II-51 M-132 I-2 II-52 M-133 I-2 II-53 M-134 I-2II-54 M-135 I-2 II-55 M-136 I-2 II-56 M-137 I-2 II-57 M-138 I-2 II-58M-139 I-2 II-59 M-140 I-2 II-60 M-141 I-2 II-61 M-142 I-2 II-62 M-143I-2 II-63 M-144 I-2 II-64 M-145 I-2 II-65 M-146 I-2 II-66 M-147 I-2II-67 M-148 I-2 II-68 M-149 I-2 II-69 M-150 I-2 II-70 M-151 I-2 II-71M-152 I-2 II-72 M-153 I-2 II-73 M-154 I-2 II-74 M-155 I-2 II-75 M-156I-2 II-76 M-157 I-2 II-77 M-158 I-2 II-78 M-159 I-2 II-79 M-160 I-2II-80 M-161 I-3 II-1 M-162 I-3 II-2 M-163 I-3 II-3 M-164 I-3 II-4 M-165I-3 II-5 M-166 I-3 II-6 M-167 I-3 II-7 M-168 I-3 II-8 M-169 I-3 II-9M-170 I-3 II-10 M-171 I-3 II-11 M-172 I-3 II-12 M-173 I-3 II-13 M-174I-3 II-14 M-175 I-3 II-15 M-176 I-3 II-16 M-177 I-3 II-17 M-178 I-3II-18 M-179 I-3 II-19 M-180 I-3 II-20 M-181 I-3 II-21 M-182 I-3 II-22M-183 I-3 II-23 M-184 I-3 II-24 M-185 I-3 II-25 M-186 I-3 II-26 M-187I-3 II-27 M-188 I-3 II-28 M-189 I-3 II-29 M-190 I-3 II-30 M-191 I-3II-31 M-192 I-3 II-32 M-193 I-3 II-33 M-194 I-3 II-34 M-195 I-3 II-35M-196 I-3 II-36 M-197 I-3 II-37 M-198 I-3 II-38 M-199 I-3 II-39 M-200I-3 II-40 M-201 I-3 II-41 M-202 I-3 II-42 M-203 I-3 II-43 M-204 I-3II-44 M-205 I-3 II-45 M-206 I-3 II-46 M-207 I-3 II-47 M-208 I-3 II-48M-209 I-3 II-49 M-210 I-3 II-50 M-211 I-3 II-51 M-212 I-3 II-52 M-213I-3 II-53 M-214 I-3 II-54 M-215 I-3 II-55 M-216 I-3 II-56 M-217 I-3II-57 M-218 I-3 II-58 M-219 I-3 II-59 M-220 I-3 II-60 M-221 I-3 II-61M-222 I-3 II-62 M-223 I-3 II-63 M-224 I-3 II-64 M-225 I-3 II-65 M-226I-3 II-66 M-227 I-3 II-67 M-228 I-3 II-68 M-229 I-3 II-69 M-230 I-3II-70 M-231 I-3 II-71 M-232 I-3 II-72 M-233 I-3 II-73 M-234 I-3 II-74M-235 I-3 II-75 M-236 I-3 II-76 M-237 I-3 II-77 M-238 I-3 II-78 M-239I-3 II-79 M-240 I-3 II-80 M-241 I-1 II-23a M-242 I-1 II-24a M-243 I-1II-25a M-244 I-1 II-26a M-245 I-1 II-45a M-246 I-1 II-81 M-247 I-1 II-82M-248 I-1 II-83 M-249 I-1 II-84 M-250 I-1 II-85 M-251 I-1 II-86 M-252I-1 II-87 M-253 I-1 II-88 M-254 I-1 II-89 M-255 I-1 II-93 M-256 I-1II-93a M-257 I-2 II-23a M-258 I-2 II-24a M-259 I-2 II-25a M-260 I-2II-26a M-261 I-2 II-45a M-262 I-2 II-81 M-263 I-2 II-82 M-264 I-2 II-83M-265 I-2 II-84 M-266 I-2 II-85 M-267 I-2 II-86 M-268 I-2 II-87 M-269I-2 II-88 M-270 I-2 II-89 M-271 I-2 II-93 M-272 I-2 II-93a M-273 I-3II-23a M-274 I-3 II-24a M-275 I-3 II-25a M-276 I-3 II-26a M-277 I-3II-45a M-278 I-3 II-81 M-279 I-3 II-82 M-280 I-3 II-83 M-281 I-3 II-84M-282 I-3 II-85 M-283 I-3 II-86 M-284 I-3 II-87 M-285 I-3 II-88 M-286I-3 II-89 M-287 I-3 II-93 M-288 I-3 II-93a M-289 I-1 II-90 M-290 I-1II-91 M-291 I-1 II-92 M-292 I-2 II-90 M-293 I-2 II-91 M-294 I-2 II-92M-295 I-3 II-90 M-296 I-3 II-91 M-297 I-3 II-92

More preferred mixtures of the present invention are mixtures ofL-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts orL-glufosinate as free acid and one compound II selected from the groupconsisting of clethodim, cycloxydim, haloxyfop, haloxyfop-methyl,haloxyfop-P, haloxyfop-P-methyl, quizalofop, quizalofop-ethyl,quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl,quizalofop-P-tefuryl, chlorimuron, chlorimuron-ethyl, foramsulfuron,halosulfuron, halosulfuron-methyl, iodosulfuron,iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron, rimsulfuron,thifensulfuron, thifensulfuron-methyl, tritosulfuron, imazamox, imazamoxammonium, imazapic, imazapic ammonium, imazapyr, imazapyrisopropylammonium, imazethapyr, imazethapyr ammonium, diclosulam,flumetsulam, florasulam, metosulam, thiencarbazone,thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil andits salts and esters, bentazone, bentazone-sodium, pyridate,carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, picolinafen, bicyclopyrone, clomazone,isoxaflutole, mesotrione, sulcotrione, tembotrione, tolpyralate,topramezone, fenquinotrione, glyphosate, glyphosate dimethylammmonium,glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metazachlor, metolachlor, S-metolachlor, pethoxamid,flufenacet, pyroxasulfone, 2,4-D and its salts and esters, clopyralidand its salts and esters, dicamba and its salts and esters, quinclorac,quinclorac dimethylammonium, quinmerac,diflufenzopyr,diflufenzopyr-sodium, cinmethylin, MCPA and its salts and esters, II-83:ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate(CAS 353292-31-6, S-3100), II-84:2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-aceticacid methyl ester (CAS 1970221-16-9), II-85:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide(CAS 2158276-22-1), II-86:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid ethyl ester (CAS 2158274-56-5), II-87:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide(CAS 2158274-53-2), II-88:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid ethyl ester (CAS 2158274-50-9) and II-89: ethyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate(CAS 2230679-62-4), II-90:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid methyl ester (CAS 2158275-73-9), II-91:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid methyl ester (CAS 2158274-96-3) and II-92: methyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate.

Thus, more preferred are mixtures M-1, M-2, M-3, M-4, M-5, M-6, M-7,M-8, M-9, M-10, M-11, M-12, M-13, M-14, M-15, M-16, M-17, M-18, M-19,M-20, M-21, M-22, M-23, M-24, M-25, M-26, M-27, M-28, M-29, M-30, M-31,M-32, M-33, M-34, M-35, M-36, M-37, M-38, M-39, M-40, M-41, M-42, M-43,M-44, M-45, M-46, M-47, M-48, M-49, M-50, M-51, M-52, M-53, M-54, M-55,M-56, M-57, M-58, M-59, M-60, M-61, M-62, M-63, M-64, M-65, M-66, M-67,M-68, M-69, M-70, M-71, M-72, M-73, M-74, M-75, M-76, M-77, M-78, M-79,M-80, M-81, M-82, M-83, M-84, M-85, M-86, M-87, M-88, M-89, M-90, M-91,M-92, M-93, M-94, M-95, M-96, M-97, M-98, M-99, M-100, M-101, M-102,M-103, M-104, M-105, M-106, M-107, M-108, M-109, M-110, M-111, M-112,M-113, M-114, M-115, M-116, M-117, M-118, M-119, M-120, M-121, M-122,M-123, M-124, M-125, M-126, M-127, M-128, M-129, M-130, M-131, M-132,M-133, M-134, M-135, M-136, M-137, M-138, M-139, M-140, M-141, M-142,M-143, M-144, M-145, M-146, M-147, M-148, M-149, M-150, M-151, M-152,M-153, M-154, M-155, M-156, M-157, M-158, M-159, M-160, M-161, M-162,M-163, M-164, M-165, M-166, M-167, M-168, M-169, M-170, M-171, M-172,M-173, M-174, M-175, M-176, M-177, M-178, M-179, M-180, M-181, M-182,M-183, M-184, M-185, M-186, M-187, M-188, M-189, M-190, M-191, M-192,M-193, M-194, M-195, M-196, M-197, M-198, M-199, M-200, M-201, M-202,M-203, M-204, M-205, M-206, M-207, M-208, M-209, M-210, M-211, M-212,M-213, M-214, M-215, M-216, M-217, M-218, M-219, M-220, M-221, M-222,M-223, M-224, M-225, M-226, M-227, M-228, M-229, M-230, M-231, M-232,M-233, M-234, M-235, M-236, M-237, M-238, M-239, M-240, M-241, M-242,M-243, M-244, M-245, M-246, M-247, M-248, M-249, M-250, M-251, M-252,M-253, M-254, M-255, M-256, M-257, M-258, M-259, M-260, M-261, M-262,M-263, M-264, M-265, M-266, M-267, M-268, M-269, M-270, M-271, M-272,M-273, M-274, M-275, M-276, M-277, M-278, M-279, M-280, M-281, M-282,M-283, M-284, M-285, M-286, M-287, M-288, M-289, M-290, M-291, M-292,M-293, M-294, M-295, M-296 and M-297.

Most preferred are mixtures M-35, M-36, M-37, M-42, M-52, M-53, M-54,M-55, M-57, M-58, M-60, M-61, M-80, M-115, M-116, M-117, M-122, M-132,M-133, M-134, M-135, M-137, M-138, M-140, M-141, M-160, M-195, M-196,M-197, M-202, M-212, M-213, M-214, M-215, M-217, M-218, M-220, M-221,M-240, M-246, M-247, M-248, M-249, M-250, M-251, M-252, M-253, M-254,M-262, M-263, M-264, M-265, M-266, M-267, M-268, M-269, M-270, M-278,M-279, M-280, M-281, M-282, M-283, M-284, M-285, M-286, M-289, M-290,M-291, M-292, M-293, M-294, M-295, M-296, M-297.

All above-referred mixtures are herein below referred to as “inventivemixtures”.

The inventive mixtures can further contain one or more insecticides,fungicides, herbicides.

The inventive mixtures can be converted into customary types ofagrochemical mixtures, e. g. solutions, emulsions, suspensions, dusts,powders, pastes, granules, pressings, capsules, and mixtures thereof.Examples for mixture types are suspensions (e.g. SC, OD, FS),emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME),capsules (e.g. CS, ZC), pastes, pastilles, wetable powders or dusts(e.g. WP, SP, WS, DP, DS), pressings (e.g. BR, TB, DT), granules (e.g.WG, SG, GR, FG, GG, MG), insecticidal articles (e.g. LN), as well as gelformulations for the treatment of plant propagation materials such asseeds (e.g. GF). These and further mixtures types are defined in the“Catalogue of pesticide formulation types and international codingsystem”, Technical Monograph No. 2, 6^(th) Ed. May 2008, CropLifeInternational.

The mixtures are prepared in a known manner, such as described by Molletand Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; orKnowles, New developments in crop protection product formulation, AgrowReports DS243, T&F Informa, London, 2005.

Suitable auxiliaries are solvents, liquid carriers, solid carriers orfillers, surfactants, dispersants, emulsifiers, wetters, adjuvants,solubilizers, penetration enhancers, protective colloids, adhesionagents, thickeners, humectants, repellents, attractants, feedingstimulants, compatibilizers, bactericides, anti-freezing agents,anti-foaming agents, colorants, tackifiers and binders.

Suitable solvents and liquid carriers are water and organic solvents,such as mineral oil fractions of medium to high boiling point, e.g.kerosene, diesel oil; oils of vegetable or animal origin; aliphatic,cyclic and aromatic hydrocarbons, e. g. toluene, paraffin,tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g. ethanol,propanol, butanol, benzylalcohol, cyclohexanol; glycols; DMSO; ketones,e.g. cyclohexanone; esters, e.g. lactates, carbonates, fatty acidesters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides,e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixturesthereof.

Suitable solid carriers or fillers are mineral earths, e.g. silicates,silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite,diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate,magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers,e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas;products of vegetable origin, e.g. cereal meal, tree bark meal, woodmeal, nutshell meal, and mixtures thereof.

Suitable surfactants are surface-active compounds, such as anionic,cationic, nonionic and amphoteric surfactants, block polymers,polyelectrolytes, and mixtures thereof. Such surfactants can be used asemulsifier, dispersant, solubilizer, wetter, penetration enhancer,protective colloid, or adjuvant. Examples of surfactants are listed inMcCutcheon's, Vol. 1: Emulsifiers & Detergents, McCutcheon'sDirectories, Glen Rock, USA, 2008 (International Ed. or North AmericanEd.)

Suitable anionic surfactants are alkali, alkaline earth or ammoniumsalts of sulfonates, sulfates, phosphates, carboxylates, and mixturesthereof. Examples of sulfonates are alkylarylsulfonates,diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates,sulfonates of fatty acids and oils, sulfonates of ethoxylatedalkylphenols, sulfonates of alkoxylated arylphenols, sulfonates ofcondensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes,sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates orsulfosuccinamates. Examples of sulfates are sulfates of fatty acids andoils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols,or of fatty acid esters. Examples of phosphates are phosphate esters.Examples of carboxylates are alkyl carboxylates, and carboxylatedalcohol or alkylphenol ethoxylates.

Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acidamides, amine oxides, esters, sugar-based surfactants, polymericsurfactants, and mixtures thereof. Examples of alkoxylates are compoundssuch as alcohols, alkylphenols, amines, amides, arylphenols, fatty acidsor fatty acid esters which have been alkoxylated with 1 to 50equivalents. Ethylene oxide and/or propylene oxide may be employed forthe alkoxylation, preferably ethylene oxide. Examples of N-subsitituedfatty acid amides are fatty acid glucamides or fatty acid alkanolamides.Examples of esters are fatty acid esters, glycerol esters ormonoglycerides. Examples of sugar-based surfactants are sorbitans,ethoxylated sorbitans, sucrose and glucose esters oralkylpolyglucosides. Examples of polymeric surfactants are home- orcopolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.

Suitable cationic surfactants are quaternary surfactants, for examplequaternary ammonium compounds with one or two hydrophobic groups, orsalts of long-chain primary amines. Suitable amphoteric surfactants arealkylbetains and imidazolines. Suitable block polymers are blockpolymers of the A-B or A-B-A type comprising blocks of polyethyleneoxide and polypropylene oxide, or of the A-B-C type comprising alkanol,polyethylene oxide and polypropylene oxide. Suitable polyelectrolytesare polyacids or polybases. Examples of polyacids are alkali salts ofpolyacrylic acid or polyacid comb polymers. Examples of polybases arepolyvinylamines or polyethyleneamines.

Suitable adjuvants are compounds, which have a neglectable or even nopesticidal activity themselves, and which improve the biologicalperformance of the inventive mixtures on the target. Examples aresurfactants, mineral or vegetable oils, and other auxilaries. Furtherexamples are listed by Knowles, Adjuvants and additives, Agrow ReportsDS256, T&F Informa UK, 2006, chapter 5.

Suitable thickeners are polysaccharides (e.g. xanthan gum,carboxymethylcellulose), anorganic clays (organically modified orunmodified), polycarboxylates, and silicates.

Suitable bactericides are bronopol and isothiazolinone derivatives suchas alkylisothiazolinones and benzisothiazolinones.

Suitable anti-freezing agents are ethylene glycol, propylene glycol,urea and glycerin.

Suitable anti-foaming agents are silicones, long chain alcohols, andsalts of fatty acids.

Suitable colorants (e.g. in red, blue, or green) are pigments of lowwater solubility and water-soluble dyes. Examples are inorganiccolorants (e.g. iron oxide, titan oxide, iron hexacyanoferrate) andorganic colorants (e.g. alizarin-, azo- and phthalocyanine colorants).

Suitable tackifiers or binders are polyvinylpyrrolidons,polyvinylacetates, polyvinyl alcohols, polyacrylates, biological orsynthetic waxes, and cellulose ethers.

Examples for mixture types and their preparation are:

i) Water-Soluble Concentrates (SL, LS)

10-60 wt % of an inventive mixture and 5-15 wt % wetting agent (e.g.alcohol alkoxylates) are dissolved in water and/or in a water-solublesolvent (e.g. alcohols) ad 100 wt %. The active substance dissolves upondilution with water.

ii) Dispersible Concentrates (DC)

5-25 wt % of an inventive mixture and 1-10 wt % dispersant (e. g.polyvinylpyrrolidone) are dissolved in organic solvent (e.g.cyclohexanone) ad 100 wt %. Dilution with water gives a dispersion

iii) Emulsifiable Concentrates (EC)

15-70 wt % of an inventive mixture and 5-10 wt % emulsifiers (e.g.calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolvedin water-insoluble organic solvent (e.g. aromatic hydrocarbon) ad 100 wt%. Dilution with water gives an emulsion.

iv) Emulsions (EW, EO, ES)

5-40 wt % of an inventive mixture and 1-10 wt % emulsifiers (e.g.calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolvedin 20-40 wt % water-insoluble organic solvent (e.g. aromatichydrocarbon). This mixture is introduced into water ad 100 wt % by meansof an emulsifying machine and made into a homogeneous emulsion. Dilutionwith water gives an emulsion.

v) Suspensions (SC, OD, FS)

In an agitated ball mill, 20-60 wt % of an inventive mixture arecomminuted with addition of 2-10 wt % dispersants and wetting agents(e.g. sodium lignosulfonate and alcohol ethoxylate), 0.1-2 wt %thickener (e.g. xanthan gum) and water ad 100 wt % to give a fine activesubstance suspension. Dilution with water gives a stable suspension ofthe active substance. For FS type mixture up to 40 wt % binder (e.g.polyvinylalcohol) is added.

vi) Water-Dispersible Granules and Water-Soluble Granules (WG, SG)

50-80 wt % of an inventive mixture are ground finely with addition ofdispersants and wetting agents (e.g. sodium lignosulfonate and alcoholethoxylate) ad 100 wt % and prepared as water-dispersible orwater-soluble granules by means of technical appliances (e. g.extrusion, spray tower, fluidized bed). Dilution with water gives astable dispersion or solution of the active substance.

vii) Water-Dispersible Powders and Water-Soluble Powders (WP, SP, WS)

50-80 wt % of an inventive mixture are ground in a rotor-stator millwith addition of 1-5 wt % dispersants (e.g. sodium lignosulfonate), 1-3wt % wetting agents (e.g. alcohol ethoxylate) and solid carrier (e.g.silica gel) ad 100 wt %. Dilution with water gives a stable dispersionor solution of the active substance.

viii) Gel (GW, GF)

In an agitated ball mill, 5-25 wt % of an inventive mixture arecomminuted with addition of 3-10 wt % dispersants (e.g. sodiumlignosulfonate), 1-5 wt % thickener (e.g. carboxymethylcellulose) andwater ad 100 wt % to give a fine suspension of the active substance.Dilution with water gives a stable suspension of the active substance.

ix) Microemulsion (ME)

5-20 wt % of an inventive mixture are added to 5-30 wt % organic solventblend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt %surfactant blend (e.g. alcohol ethoxylate and arylphenol ethoxylate),and water ad 100%. This mixture is stirred for 1 h to producespontaneously a thermodynamicallystable microemulsion.

x) Microcapsules (CS)

An oil phase comprising 5-50 wt % of an inventive mixture, 0-40 wt %water insoluble organic solvent (e.g. aromatic hydrocarbon), 2-15 wt %acrylic monomers (e.g. methylmethacrylate, methacrylic acid and a di- ortriacrylate) are dispersed into an aqueous solution of a protectivecolloid (e.g. polyvinyl alcohol). Radical polymerization initiated by aradical initiator results in the formation of poly(meth)acrylatemicrocapsules. Alternatively, an oil phase comprising 5-50 wt % of aninventive mixture according to the invention, 0-40 wt % water insolubleorganic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer(e.g. diphenylmethene-4,4′-diisocyanatae) are dispersed into an aqueoussolution of a protective colloid (e.g. polyvinyl alcohol). The additionof a polyamine (e.g. hexamethylenediamine) results in the formation ofpolyurea microcapsules. The monomers amount to 1-10 wt %. The wt %relate to the total CS mixture.

xi) Dustable Powders (DP, DS)

1-10 wt % of an inventive mixture are ground finely and mixed intimatelywith solid carrier (e.g. finely divided kaolin) ad 100 wt %.

x) Granules (GR, FG)

0.5-30 wt % of an inventive mixture is ground finely and associated withsolid carrier (e.g. silicate) ad 100 wt %. Granulation is achieved byextrusion, spray-drying or fluidized bed.

xii) Ultra-Low Volume Liquids (UL)

1-50 wt % of an inventive mixture are dissolved in organic solvent (e.g.aromatic hydrocarbon) ad 100 wt %.

The mixtures types i) to xii) may optionally comprise furtherauxiliaries, such as 0.1-1 wt % bactericides, 5-15 wt % anti-freezingagents, 0.1-1 wt % anti-foaming agents, and 0.1-1 wt % colorants.

The resulting agrochemical mixtures generally comprise between 0.01 and95%, preferably between 0.1 and 90%, and in particular between 0.5 and75%, by weight of active substance. The active substances are employedin a purity of from 90% to 100%, preferably from 95% to 100% (accordingto NMR spectrum).

Solutions for seed treatment (LS), Suspoemulsions (SE), flowableconcentrates (FS), powders for dry treatment (DS), water-dispersiblepowders for slurry treatment (WS), water-soluble powders (SS), emulsions(ES), emulsifiable concentrates (EC) and gels (GF) are usually employedfor the purposes of treatment of plant propagation materials,particularly seeds.

The mixtures in question give, after two-to-tenfold dilution, activesubstance concentrations of from 0.01 to 60% by weight, preferably from0.1 to 40%, in the ready-to-use preparations. Application can be carriedout before or during sowing. Methods for applying the inventive mixturesand mixtures thereof, respectively, on to plant propagation material,especially seeds include dressing, coating, pelleting, dusting, soakingand in-furrow application methods of the propagation material.Preferably, the inventive mixtures or the mixtures thereof,respectively, are applied on to the plant propagation material by amethod such that germination is not induced, e. g. by seed dressing,pelleting, coating and dusting.

Various types of oils, wetters, adjuvants, fertilizer, ormicronutrients, and further pesticides (e.g. herbicides, insecticides,fungicides, growth regulators, safeners) may be added to the activesubstances or the inventive mixtures comprising them as premix or, ifappropriate not until immediately prior to use (tank mix). These agentscan be admixed with the inventive mixtures in a weight ratio of 1:100 to100:1, preferably 1:10 to 10:1.

The user applies the mixture according to the invention usually from apredosage device, a knapsack sprayer, a spray tank, a spray plane, or anirrigation system. Usually, the agrochemical mixture is made up withwater, buffer, and/or further auxiliaries to the desired applicationconcentration and the ready-to-use spray liquor or the agrochemicalmixture according to the invention is thus obtained. Usually, 20 to 2000liters, preferably 50 to 400 liters, of the ready-to-use spray liquorare applied per hectare of agricultural useful area.

The inventive mixtures provide excellent pre-plant burn-down, pre- andpost-emergence control of weeds in corn, including corn that is tolerantto herbicides including glufosinate. Thus, in the methods and uses ofthe invention, the compounds present in the inventive mixtures can beapplied for pre-plant burn-down (to control emerged weeds prior toplanting), pre-emergence (before the emergence of undesirablevegetation) or post-emergence (i.e., during and/or after emergence ofthe undesirable vegetation).

Thus, the invention relates to a method of an inventive mixture forcontrolling undesirable vegetation in corn, including corn that istolerant to herbicides including glufosinate, which comprises applyingthe compounds present in the inventive mixtures to a locus of plantedcrops where undesirable vegetation occurs or might occur. Theapplication is done before the emergence of undesirable vegetation orduring and/or after emergence of the undesirable vegetation. Theapplication can be done after seeding of the corn or during and/or afteremergence of the corn.

The term “locus”, as used herein, means the area in which the vegetationor plants are growing or will grow, typically a field.

As used herein, the terms “controlling” and “combating” are synonyms.

As used herein, the terms “undesirable vegetation”, “undesirablespecies”, “undesirable plants”, “harmful plants”, “undesirable weeds”,or “harmfull weeds” are synonyms.

When using the inventive mixtures in the methods of the presentinvention, the active compounds present in the inventive mixtures can beapplied simultaneously or in succession, where undesirable vegetationmay occur. Herein, it is immaterial whether compounds present in theinventive mixtures are formulated jointly or separately and appliedjointly or separately, and, in the case of separate application, inwhich order the application takes place. It is only necessary, that thecompounds present in the inventive mixtures are applied in a time frame,which allows simultaneous action of the active ingredients on theundesirable plants.

In the above-mentioned methods of controlling weeds by application ofthe inventive mixtures, the inventive mixtures have an outstandingherbicidal activity against a broad spectrum of economically importantmonocotyledonous and dicotyledonous harmful plants. The inventivemixtures also act efficiently on perennial weeds which produce shootsfrom rhizomes, rootstocks or other perennial organs and which aredifficult to control. In this context, it does not matter whether thecompounds of the inventive mixtures are applied before sowing,pre-emergence or post-emergence. Pre-plant burn-down, post-emergenceapplication, or early pre-sowing or pre-emergence application, arepreferred.

Both L-glufosinate alone as well as, in the methods of the presentinvention, the inventive mixtures are suitable for controlling a largenumber of harmful plants in agricultural crops, includingmonocotyledonous weeds, in particular annual weeds such as gramineousweeds (grasses) including Echinochloa species such as barnyardgrass(Echinochloa crusgalli var. crus-galli), Echinchloa walteri (Pursh)Heller, jungle rice (Echinochloa colona), Echinochloa crus-pavonis,Echinochloa oryzicola, Digitaria species such as crabgrass (Digitariasanguinalis), Digitaria horizontalis, sourgrass (Digitaria insularis) ornaked crabgrass (Digitaria nuda), Setaria species such as green foxtail(Setaria viridis), giant foxtail (Setaria faberii), yellow foxtail(Setaria glauca or Setaria pumila) or Setaria verticillata, Sorghumspecies such as johnsongrass (Sorghum halepense Pers.), Avena speciessuch as wild oats (Avena fatua), Avena sterillis or Avena strigosa,Cenchrus species such as Cenchrus species such as field sandbur(Cenchrus pauciflorus) or Cenchrus echinatus, Bromus species such asBromus japonicus Thunb, Bromus sterilis or Bromus tectorum, Loliumspecies, Phalaris species such as Phalaris brachystachys, Phalaris minoror Phalaris persicaria, Eriochloa species, Panicum species such as fallpanicum (Panicum dichotomiflorum), Panicum fasciculatum or Panicummaximum, Brachiaria species, annual bluegrass (Poa annua), Alopecurusspecies such as blackgrass (Alopecurus myosuroides), Alopecurus aequalisSobol or Alopecurus japonicus Steud, Aegilops species such as Aegilopscylindrica or Aegylops tauschii, Apera spica-venti, Eleusine indica,Cynodon dactylon, couch grass (Agropyron repens or Elymus repens),Agrostis alba, Beckmannia syzigachne (Steud.) Fernald, Chloris speciessuch as Chloris virgata, Commelina species such as Commelinabenghalensis, Commelina communis, Commelina diffusa or Commelina erecta,Dactyloctenium aegyptium, Hordeum jubatum, Hordeum leporinum, Imperatacylindrica, lschaemum rogusum, Ixophorus unisetus, Leerisa hexandra,Leersia japonica, Leptochloa species such as Leptochloa chinensis,Leptochloa fascicularis, Leptochloa filiformis or Leptochloa panicoides,Lolium species such as Lolium multiflorum, Lolium perenne, Loliumpersicum or rigid ryegrass (Lolium rigidum), Luziola subintegra,Murdannia nudiflora (L.) Brenan, Oryza latifolia, Oryza rufipogon,Paspalum distichum, Paspalum species, Pennisetum americanum, Pennisetumpurpureum, Phleum paniculatum, Phragmites australia, Ploypogon fugax.N., Poa species such as Poa annua or Poa trivialis L., Puccinelliadistans, Rottboellia cochinchinensis, Sclerochloa kengiana (Ohwi)Tzvel., Trichloris crinita, Urochloa or Brachiaria species such asBrachiaria decumbens, Brachiaria plantaginea, Brachiaria platyphylla,Urochloa panicoides, Urochloa ramosa and the like.

Both L-glufosinate alone as well as the inventive mixtures are alsosuitable for controlling a large number of dicotyledonous weeds, inparticular broad leaf weeds including Polygonum species such as wildbuckwheat (Polygonum convolvolus), Polygonum pensilvanicum, Polygonumpersicaria or prostrate knotweed (Polygonum aviculare), Amaranthusspecies such as pigweed (Amaranthus retroflexus), Palmer amaranth(Amaranthus palmeri), tall waterhemp (Amaranthus tuberculatus orAmaranthus rudis), redroot pigweed (Amaranthus retroflexus), greenamaranth (Amaranthus hybridus), purple amaranth (Amaranthus lividus),prickly amaranth (Amaranthus spinosus) or Amaranthus quitensis,Chenopodium species such as common lambsquarters (Chenopodium album L.),Chenopodium serotinum or Quinoa (Chenopodium quinoa), Sida species suchas prickly Sida (Sida spinosa L.), Ambrosia species such as commonragweed (Ambrosia artemisiifolia) or giant ragweed (Ambrosia trifida),Acanthospermum species, Anthemis species such as Anthemis arvensis orAnthemis cotula, Atriplex species, Cirsium species such as Cirsiumarvense, Convolvulus species such as field bindweed (Convolvulusarvensis), Conyza species such as horseweed (Conyza canadensis, Erigeroncanadensis) or hairy fleabane (Conyza bonariensis, Erigeronbonariensis), Cassia species, Datura species such as jimsonweed (Daturastramonium), Euphorbia species such as toothed spurge (Euphorbiadentata), Euphorbia hirta, Euphorbia helioscopia or fireplant (Euphorbiaheterophylla), Geranium species such as Geranium donianum or Geraniumpusillum, Galinsoga species, morningglory (Ipomoea species), Lamiumspecies such as henbit dead-nettle (Lamium amplexicaule), Malva speciessuch as dwarf mallow (Malva neglecta) or cheeseweed (Malwa parviflora),Matricaria species such as chamomile (Matricaria chamomilla) orMatricaria inodora, Sysimbrium species, Solanum species such as blacknightshade (Solanum nigrum), Xanthium species, Veronica species such asVeronica polita, Viola species, common chickweed (Stellaria media),velvetleaf (Abutilon theophrasti), Sesbania species such as Sesbaniaexaltata, Sesbania herbacea or hemp Sesbania (Sesbania exaltata Cory),Anoda cristata, Bidens species such as Bidens frondosa or Bidens pilosa,Brassica kaber, Capsella species such as Capsella media or Capsellabursa-pastoris, Centaurea cyanus, Galeopsis tetrahit, Galium aparine,Helianthus annuus, Desmodium tortuosum, Kochia scoparia, Mercurialisannua, Myosotis arvensis, Papaver rhoeas, Raphanus species such as wildradish (Raphanus raphanistrum), Salsola species such as Salsola tragusor Salsola kali, Sinapis arvensis, Sonchus species sucha Sonchus asper,Sonchus arvensis or Sonchus oleraceus, Thlaspi arvense, Tagetes minuta,Richardia species such as Richardia scabra or Richardia brasiliensis,Aeschynomeme species such as Aeschynomene denticulata, Aeschynomeneindica or Aeschynomene rudis, Alisma species such as Alismacanaliculatum or Alisma plantago-aquatica, Borreria species such asBorreria verticillata, Brassica rapa, Carduus acanthoides, Parietariadebilis, Portulaca oleracea, Ipomoea species such as Ipomoeagrandifolia, Ipomoea hederacea, Ipomoea indivisa, Ipomoea lacunose,Ipomoea lonchophylla or Ipomoea wrightii, Senna obtusifolia, Sidaspecies such as arrowleaf sida (Sida rhombifolia) or prickly Sida (Sidaspinosa), Spermacoce latifolia, Tridax procumbens, Trianthemaportulacastrum, Parthenium hysterophorus, Portulaca oleracea, Acalyphaaustralis, Ammi majus, Atriplex species, Orobanche species, Mercurialisannua, Cirsium arvense, Calystegia sepium, Stellaria media, Lamiumspecies, Viola species, Celosia argentea, Melampodium divaricatum,Cleome viscosa, Molugo verticilatus, Borhevia erecta, Gomphrena species,Nicandra physalodes, Ricinus communis, Geranium dissectum, Alternantheraspecies such as Althernanthera philoxeroides or Alternanthera tenella,Ammannia species such as Ammania coccinea, Anacamtodon fortunei Mitt.,Anagallis arvensis, Aneilema keisak, Arenaria serpyllifolia, Argemonemexicana, Asphodelus tenuifolius, Atriplex patula, Bacopa rotundifolia,Brassica napus, Caperonia species sucha as Caperonia castaneifolia orCaperonia palustris, Cephalanoplos segetum, Corynopus didymus, Crepiscapillaris, Crepis tectorum, Croton lobatus, Descuminia sophia (L.),Descurainia pinnata, Echinodorus grandiflorus, Eclipta alba, Ecliptaprostrata, Eichhornia crassipes, Eleocharis species, Equisetum arvense,Fallopia convolvulus, Fallopia convolvulus, Heteranthera limosa,Jussiaea species, Kallstroemia maxima, Lactuca serriola, Lathyrusaphaca, Launea mudicaulis, Leucas chinensis, Limnocharis flava,Lindernia dubia, Lindernia pyxidaria, Litospermum arvense, Ludwigiaspecies such as Ludwigia octovallis, Macroptilium lathyroides, Malachiumaquaticum (L.), Melilotus species, Merremia aegyptia, Momordicacharantia, Monochoria hastate, Monochoria vaginalis, Mucuna species,Murdannia nudiflora, Oxalis neaei, Phylanthus species, Physalis species,Pistia stratiotes, Potamogeton distinctus, Rorippa islandica, Rotalaindica, Rotala ramosior, Rumex dentatus, Rumex obtusifolius, Sagittariamontevidensis, Sagittaria pygmaea Miq., Sagittaria sagittifolia,Sagittaria trifolia L., Senecio vulgaris, Sicyos polyacanthus, Silenegallica, chenopo Sisymbrium species such as Sisymbrium oficinale,Solanum species, Spergula arvensis, Sphenoclea zeylanica, Trianthemaspp., Tripleurospermum inodorum, Veronica species such as Veronicapersica or Veronica polita Vicia sativa and the like.

Both L-glufosinate alone as well as the inventive mixtures are alsosuitable for controlling a large number of annual and perennial sedgeweeds including Cyperus species such as purple nutsedge (Cyperusrotundus L.), yellow nutsedge (Cyperus esculentus L.), hime-kugu(Cyperus brevifolius H.), sedge weed (Cyperus microiria Steud), riceflatsedge (Cyperus iria L.), Cyperus difformis, Cyperus difformis L.,Cyperus esculentus, Cyperus ferax, Cyperus flavus, Cyperus iria, Cyperuslanceolatus, Cyperus odoratus, Cyperus rotundus, Cyperus serotinusRottb., Eleocharis acicularis, Eleocharis kuroguwai, Fimbristylisdichotoma, Fimbristylis miliacea, Scirpus grossus, Scirpus juncoides,Scirpus juncoides Roxb, Scirpus or Bolboschoenus maritimus, Scirpus orSchoenoplectus mucronatus, Scirpus planiculmis Fr. Schmidt and the like.

Both L-glufosinate alone as well as the inventive mixtures are alsosuitable for controlling weeds that are resistant to commonly usedherbicides such as, for example, weeds that are resistant to glyphosate,weeds that are resistant to auxin inhibitor herbicides such as e. g.2,4-D or dicamba, weeds that are resistant to photosynthesis inhibitorssuch as e. g. atrazine, weeds that are resistant to ALS inhibitors suchas e. g. sulfonylureas, imidazolinones or triazolopyrimidines, weedsthat are resistant to ACCase inhibitors such as e. g. clodinafop,clethodim or pinoxaden or weeds that are resistant toprotoporphyrinogen-IX-oxidase inhibitors such as e. g. sulfentrazone,flumioxazine, fomesafen or acifluorfen, for example the weeds that arelisted in the International Survey of Resistant Weeds(http://www.weedscience.org/Summary/SpeciesbySOATable.aspx). Inparticular, they are suitable for controlling the resistant weeds thatare listed in the International Survey of Resistant Weeds, for exampleACCase resistant Echinochloa crus-galli, Avena fatua, Alopecurusmyosuroides, Echinochloa colona, Alopecurus japonicus, Bromus tectorum,Hordeum murinum, Ischaemum rugosum, Setaria viridis, Sorghum halepense,Alopecurus aequalis, Apera spicaventi, Avena sterilis, Beckmanniaszygachne, Bromus diandrus, Digitaria sanguinalis, Echinocloa oryzoides,Echinochloa phyllopogon, Phalaris minor, Phalaris paradoxa, Setariafaberi, Setaria viridis, Brachypodium distachyon, Bromus diandrus,Bromus sterilis, Cynosurus echinatus, Digitaria insularis, Digitariaischaemum, Leptochloa chinensis, Phalaris brachystachis, Rotboelliacochinchinensis, Digitaria ciliaris, Ehrharta longiflora, Eriochloapunctata, Leptochloa panicoides, Lolium persicum, Polypogon fugax,Sclerochloa kengiana, Snowdenia polystacha, Sorghum sudanese andBrachiaria plantaginea, ALS inhibitor resistant Echinochloa crus-galli,Poa annua, Avena fatua, Alopecurus myosuroides, Echinochloa colona,Amaranthus hybridus, Amaranthus palmeri, Amaranthus rudis, Conyzasumatrensis, Amaranthus retroflexus, Ambrosia artemisifolia, Conyzacanadensis, Kochia scoparia, Raphanus raphanistrum, Senecio vernalis,Alopecurus japonicus, Bidens pilosa, Bromus tectorum, Chenopodium album,Conyza bonariensis, Hordeum murinum, lschaemum rugosum, Seneciovulgaris, Setaria viridis, Sisymbrium orientale, Sorghum halepense,Alopecurus aequalis, Amaranthus blitum, Amaranthus powellii, Aperaspica-venti, Avena sterilis, Brassica rapa, Bromus diandrus, Descurainiasophia, Digitaria sanguinalis, Echinochloa oryzoides, Echinochloaphyllopogon, Euphorbia heterophylla, Lactuca serriola, Phalaris minor,Phalaris paradoxa, Setaria faberi, Setaria viridis, Sinapis arvensis,Solanum ptycanthum, Sonchus oleraceus, Stellaria media, Amaranthusblitoides, Amaranthus spinosus, Amaranthus viridis, Ambrosia trifida,Bidens subalternans, Bromus diandrus, Bromus sterilis, Capsellabursa-pastoris, Centaurea cyanus, Cynosurus echinatus, Cyperusdifformis, Fimbristilis miliacea, Galeopsis tetrahit, Galium aparine,Galium spurium, Helianthus annuus, Hirschfeldia incana, Limnocharisflava, Limnophila erecta, Papaver rhoeas, Parthenium hysterophorus,Phalaris brachystachis, Polygonum convolvulus, Polygonum lapathifolium,Polygonum persicaria, Ranunculus acris, Rottboellia cochinchinensis,Sagittaria montevidensis, Salsola tragus, Schoenoplectus mucronatus,Setaria pumila, Sonchus asper, Xanthium strumarium, Ageratum conyzoides,Alisma canaliculatum, Alisma plantago-aquatica, Ammannia auriculata,Ammannia coccinea, Ammannia arvensis, Anthemis cotula, Bacoparotundifolia, Bifora radians, Blyxa aubertii, Brassica tournefortii,Bromus japonicus, Bromus secalinus, Lithospermum arvense, Camelinamicrocarpa, Chamaesyce maculata, Chrysanthemum coronarium, Clidemiahirta, Crepis tectorum, Cuscuta pentagona, Cyperus brevifolis, Cyperuscompressus, Cyperus esculentus, Cyperus iria, Cyperus odoratus,Damasonium minus, Diplotaxis erucoides, Diplotaxis tenuifolia, Dopatrumjunceum, Echium plantagineum, Elatine triandra, Eleocharis acicularis,Erucaria hispanica, Erysimum repandum, Galium tricornutum, Ivaxanthifolia, Ixophorus unisetus, Lamium amplexicaule, Limnophiliasessiliflora, Lindernia dubia, Lindernia micrantha, Linderniaprocumbens, Ludwigia prostrata, Matricaria recutita, Mesembryanthemumcrystallinum, Monochoria korsakowii, Monochoria vaginalis, Myosotonaquaticum, Neslia paniculata, Oryza sativa var. sylvatica, Pentziasuffruticosa, Picris hieracioides, Raphanus sativus, Rapistrum rugosum,Rorippa indica, Rotala indica, Rotala pusilla, Rumex dentatus,Sagittaria guayensis, Sagittaria pygmaea, Sagittaria trifolia,Schoenoplectus fluviatilis, Schoenoplectus juncoides, Schoenoplectuswallichii, Sida spinosa, Silene gallica, Sinapis alba, Sisymbriumthellungii, Sorghum bicolor, Spergula arvensis, Thlaspi arvense,Tripleurospermum perforatum, Vaccaria hispanica and Vicia sativa,photosynthesis inhibitor resistant Echinochloa crus-galli, Poa annua,Alopecurus myosuroides, Echinochloa colona, Amaranthus hybridus,Amaranthus palmeri, Amaranthus rudis, Conyza sumatrensis, Amaranthusretroflexus, Ambrosia artemisifolia, Conyza canadensis, Kochia scoparia,Raphanus raphanistrum, Senecio vernalis, Alopecurus japonicus, Bidenspilosa, Bromus tectorum, Chenopodium album, Conyza bonariensis,Ischaemum rugosum, Senecio vulgaris, Setaria viridis, Sisymbriumorientale, Amaranthus blitum, Amaranthus powellii, Apera spica-venti,Beckmannia syzigachne, Brassica rapa, Digitaria sanguinalis, Euphorbiaheterophylla, Phalaris minor, Phalaris paradoxa, Setaria faberi, Setariaviridis, Sinapis arvensis, Solanum ptycanthum, Stellaria media,Amaranthus blitoides, Amaranthus viridis, Bidens subalternans,Brachypodium distachyon, Capsella bursa-pastoris, Chloris barbata,Cyperus difformis, Echinochloa erecta, Epilobium ciliatum, Polygonumaviculare, Polygonum convolvulus, Polygonum lapathifolium, Polygonumpersicaria, Portulaca oleracea, Schoenoplectus mucronatus, Setariapumila, Solanum nigrum, Sonchus asper, Urochloa panicoides, Vulpiabromoides, Abutilon theophrasti, Amaranthus albus, Amaranthus cruentus,Arabidopsis thaliana, Arenaria serpyllifolia, Bidens tripartita,Chenopodium album, Chenopodium ficifolium, Chenopodium polyspermum,Crypsis schoenoides, Datura stramonium, Epilobium tetragonum, Galinsogaciliata, Matricaria discoidea, Panicum capillare, Panicumdichotomiflorum, Plantago lagopus, Polygonum hydopiper, Polygonumpensylvanicum, Polygonum monspeliensis, Rostraria, smyrnacea, Rumexacetosella, Setaria verticillata and Urtica urens, PS-I-electrondiversion inhibitor resistant Poa annua, Conyza sumatrensis, Conyzacanadensis, Alopecurus japonicus, Bidens pilosa, Conyza bonariensis,Hordeum murinum, lschaemum rugosum, Amaranthus blitum, Solanumptycanthum, Arctotheca calendula, Epilobium ciliatum, Hedyotisverticillata, Solanum nigrum, Vulpia bromoides, Convolvulus arvensis,Crassocephalum crepidioides, Cuphea carthagensis, Erigeronphiladelphicus, Gamochaeta pensylvanica, Landoltia punctata, Lepidiumvirginicum, Mazus fauriei, Mazus pumilus, Mitracarpus hirtus,Sclerochloa dura, Solanum americanum and Youngia japonica, glyphosateresistant Poa annua, Echinochloa colona, Amaranthus hybridus, Amaranthuspalmeri, Amaranthus rudis, Conyza sumatrensis, Ambrosia artemisifolia,Conyza canadensis, Kochia scoparia, Raphanus raphanistrum, Bidenspilosa, Conyza bonariensis, Hordeum murinum, Sorghum halepense, Brassicarapa, Bromus diandrus, Lactuca serriola, Sonchus oleraceus, Amaranthusspinosus, Ambrosia trifida, Digitaria insularis, Hedyotis verticillata,Helianthus annuus, Parthenium hysterophorus, Plantago lanceolata,Salsola tragus, Urochloa panicoides, Brachiaria eruciformis, Bromusrubens, Chloris elata, Chloris truncata, Chloris virgata, Cynodonhirsutus, Lactuca saligna, Leptochloa virgata, Paspalum paniculatum andTridax procumbens, microtubule assembly inhibitor resistant Echinochloacrus-galli, Poa annua, Avena fatua, Alopecurus myosuroides, Amaranthuspalmeri, Setaria viridis, Sorghum halepense, Alopecurus aequalis,Beckmannia syzigachne and Fumaria densifloria, auxin herbicide resistantEchinochloa crus-galli, Echinochloa colona, Amaranthus hybridus,Amaranthus rudis, Conyza sumatrensis, Kochia scoparia, Raphanusraphanistrum, Chenopodia album, Sisymbrium orientale, Descurainiasophia, Lactuca serriola, Sinapis arvensis, Sonchus oleraceus, Stellariamedia, Arctotheca calendula, Centaurea cyanus, Digitaria ischaemum,Fimbristylis miliacea, Galeopsis tetrahit, Galium aparine, Galiumspurium, Hirschfeldia incana, Limnocharis flava, Limnocharis erecta,Papaver rhoeas, Plantago lanceolata, Ranunculus acris, Carduus nutans,Carduus pycnocephalus, Centaurea soltitialis, Centaurea stoebe ssp.Micranthos, Cirsium arvense, Commelina diffusa, Echinochloacrus-pavonis, Soliva sessilis and Sphenoclea zeylanica, HPPD inhibitorresistant Amaranthus palmeri and Amaranthus rudis, PPO inhibitorresistant Acalypha australis, Amaranthus hybridus, Amaranthus palmeri,Amaranthus retroflexus, Amaranthus rudis, Ambrosia artemisifolia, Avenafatua, Conyza sumatrensis, Descurainia sophia, Euphorbia heterophyllaand Senecio vernalis, carotenoid biosynthesis inhibitor resistantHydrilla verticillata, Raphanus raphanistrum, Senecio vernalis andSisymbrium orientale, VLCFA inhibitor resistant Alopecurus myosuroides,Avena fatua and Echinochloa crus-galli.

If the compounds of the inventive mixtures are applied to the soilsurface before germination, then the weed seedlings are either preventedcompletely from emerging, or the weeds grow until they have reached thecotyledon stage but then their growth stops, and, eventually, afterthree to four weeks have elapsed, they die completely.

If the active compounds of the inventive mixtures are appliedpost-emergence to the green parts of the plants, growth likewise stopsdrastically a very short time after the treatment and the weed plantsremain at the growth stage of the point of time of application, or theydie completely after a certain time, so that in this manner competitionby the weeds, which is harmful to the corn plants, is eliminated at avery early point in time and in a sustained manner.

When the active compounds of the inventive mixtures are used jointly,superadditive (=synergistic) effects are observed. This means that theeffect in the combinations exceeds the expected total of the effects ofthe individual herbicides employed. The synergistic effects allow theapplication rate to be reduced, a broader spectrum of broad-leaved weedsand weed grasses to be controlled, the herbicidal effect to take placemore rapidly, the duration of action to be longer, the harmful plants tobe controlled better while using only one, or few, applications, and theapplication period which is possible to be extended. In some cases,uptake of the compositions also reduces the amount of harmfulconstituents in the crop plant, such as nitrogen or oleic acid.

The active compounds of the inventive mixtures can be used jointly or insuccession. They can also conveniently be combined with furtherherbicide treatments to treatment combinations that ensure a morecomplete or long-lasting weed control, or to ensure control of weedsthat are resistant against certain herbicides through combined action ofmutiple herbicides with different modes of action. In particular, theactive compounds of the inventive mixtures and further herbicides can beused in any of the treatment combinations outlined below that consist ofpre-plant burn down, pre-emergence and post-emergence treatments. Thesetreatment combinations can be particularly suitable if the corn istolerant to the action of one or more herbicides present in thetreatment combination, including tolerance that is a result of breedingand/or genetic modification. Such tolerant plants include glufosinatetolerant corn, glyphosate tolerant corn and corn that is tolerant toHPPD herbicides (e. g. isoxaflutole, topramezone, mesotrione,tembotrione, bicyclopyrone, fenquinotrione), auxin herbicides (e. g.2,4-D, dicamba) and/or PPO herbicides (e. g. carfentrazone-ethyl,saflufenacil, sulfentrazone, trifludimoxazin, pyraflufen-ethyl,tiafenacil, II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate(CAS 353292-31-6, S-3100).

The following active compounds of the inventive mixtures and furtherherbicides are particularly suitable as pre-plant burn-down weed controlcomponents in such treatment combinations: L-Glufosinate, L-glufosinateammonium, L-glufosinate sodium, glyphosate, glyphosate dimethylammonium,glyphosate potassium, glyphosate isopropylammonium, paraquat,tiafenacil, trifludimoxazin, saflufenacil, sulfentrazone, flumioxazin,fomesafen, carfentrazone-ethyl, II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate(CAS 353292-31-6, S-3100), 2,4-D, 2,4-D choline salt, dicamba, dicambaethanolamine salt, dicamba diglycolamine salt, dicamba potassium anddicamba BAPMA salt (i. e. dicamba N,N-bis(3-aminopropyl)methylaminesalt).

The following active compounds of the inventive mixtures and furtherherbicides are particularly suitable as pre-emergence weed controlcomponents in such treatment combinations: Atrazine, acetochlor,metolachlor, (S)-metolachlor, dimethenamid, dimethenamid-P,pyroxasulfone, thiencarbazone-methyl, flumetsulam, trifludimoxazin,saflufenacil, isoxaflutole, bicyclopyrone, tembotrione and mesotrione.

The following active compounds of the inventive mixtures and furtherherbicides are particularly suitable for post-emergence weed controlcomponents in such treatment combinations: L-Glufosinate, L-glufosinateammonium, L-glufosinate sodium, glyphosate, glyphosate dimethylammonium,glyphosate potassium, glyphosate isopropylammonium, rimsulfuron,thifensulfuron-methyl, thiencarbazone-methyl, atrazine, dimethenamid-P,isoxaflutole, topramezone, bicyclopyrone, tembotrione, mesotrione,diflufenzopyr, diflufenzopyr sodium, 2,4-D, 2,4-D choline salt, dicamba,dicamba sodium, dicamba ethanolamine salt, dicamba diglycolamine salt,dicamba potassium and dicamba BAPMA salt.

Particularly suitable treatment combinations of active compounds of theinventive mixtures and further herbicides are:

The treatment combinations 1.1 to 1.383 in which one of the treatmentcombinations listed in the following table is combined withpost-emergence use of L-glufosinate.

Treatment combination Pre-plant burn-down Pre-emergence 1 L-GlufosinateAtrazine 2 L-Glufosinate Acetochlor 3 L-Glufosinate Metolachlor 4L-Glufosinate (S)-Metolachlor 5 L-Glufosinate Dimethenamid 6L-Glufosinate Dimethenamid-P 7 L-Glufosinate Pyroxasulfone 8L-Glufosinate Thiencarbazone-methyl 9 L-Glufosinate Flumetsulam 10L-Glufosinate Trifludimoxazin 11 L-Glufosinate Saflufenacil 12L-Glufosinate Isoxaflutole 13 L-Glufosinate Bicyclopyrone 14L-Glufosinate Tembotrione 15 L-Glufosinate Mesotrione 16 L-GlufosinateAtrazine + (S)-metolachlor + benoxacor 17 L-Glufosinate Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 18L-Glufosinate Tembotrione + isoxadifen-ethyl 19 L-GlufosinateTembotrione + thiencarbazone-methyl + isoxadifen-ethyl 20 L-GlufosinateIsoxaflutole + cyprosulfamide 21 L-Glufosinate Isoxaflutole +thiencarbazone-methyl + cyprosulfamide 22 L-Glufosinate Acetochlor +flumetsulam + clopyralid 23 L-Glufosinate Saflufenacil + dimethenamid-P24 L-Glufosinate ammonium Atrazine 25 L-Glufosinate ammonium Acetochlor26 L-Glufosinate ammonium Metolachlor 27 L-Glufosinate ammonium(S)-Metolachlor 28 L-Glufosinate ammonium Dimethenamid 29 L-Glufosinateammonium Dimethenamid-P 30 L-Glufosinate ammonium Pyroxasulfone 31L-Glufosinate ammonium Thiencarbazone-methyl 32 L-Glufosinate ammoniumFlumetsulam 33 L-Glufosinate ammonium Trifludimoxazin 34 L-Glufosinateammonium Saflufenacil 35 L-Glufosinate ammonium Isoxaflutole 36L-Glufosinate ammonium Bicyclopyrone 37 L-Glufosinate ammoniumTembotrione 38 L-Glufosinate ammonium Mesotrione 39 L-Glufosinateammonium Atrazine + (S)-metolachlor + benoxacor 40 L-Glufosinateammonium Atrazine + (S)-metolachlor + mesotrione + bicyclopyrone +benoxacor 41 L-Glufosinate ammonium Tembotrione + isoxadifen-ethyl 42L-Glufosinate ammonium Tembotrione + thiencarbazone-methyl +isoxadifen-ethyl 43 L-Glufosinate ammonium Isoxaflutole + cyprosulfamide44 L-Glufosinate ammonium Isoxaflutole + thiencarbazone-methyl +cyprosulfamide 45 L-Glufosinate ammonium Acetochlor + flumetsulam +clopyralid 46 L-Glufosinate ammonium Saflufenacil + dimethenamid-P 47L-Glufosinate sodium Atrazine 48 L-Glufosinate sodium Acetochlor 49L-Glufosinate sodium Metolachlor 50 L-Glufosinate sodium (S)-Metolachlor51 L-Glufosinate sodium Dimethenamid 52 L-Glufosinate sodiumDimethenamid-P 53 L-Glufosinate sodium Pyroxasulfone 54 L-Glufosinatesodium Thiencarbazone-methyl 55 L-Glufosinate sodium Flumetsulam 56L-Glufosinate sodium Trifludimoxazin 57 L-Glufosinate sodiumSaflufenacil 58 L-Glufosinate sodium Isoxaflutole 59 L-Glufosinatesodium Bicyclopyrone 60 L-Glufosinate sodium Tembotrione 61L-Glufosinate sodium Mesotrione 62 L-Glufosinate sodium Atrazine +(S)-metolachlor + benoxacor 63 L-Glufosinate sodium Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 64L-Glufosinate sodium Tembotrione + isoxadifen-ethyl 65 L-Glufosinatesodium Tembotrione + thiencarbazone-methyl + isoxadifen-ethyl 66L-Glufosinate sodium Isoxaflutole + cyprosulfamide 67 L-Glufosinatesodium Isoxaflutole + thiencarbazone-methyl + cyprosulfamide 68L-Glufosinate sodium Acetochlor + flumetsulam + clopyralid 69L-Glufosinate sodium Saflufenacil + dimethenamid-P 70 GlyphosateAtrazine 71 Glyphosate Acetochlor 72 Glyphosate Metolachlor 73Glyphosate (S)-Metolachlor 74 Glyphosate Dimethenamid 75 GlyphosateDimethenamid-P 76 Glyphosate Pyroxasulfone 77 GlyphosateThiencarbazone-methyl 78 Glyphosate Flumetsulam 79 GlyphosateTrifludimoxazin 80 Glyphosate Saflufenacil 81 Glyphosate Isoxaflutole 82Glyphosate Bicyclopyrone 83 Glyphosate Tembotrione 84 GlyphosateMesotrione 85 Glyphosate Atrazine + (S)-metolachlor + benoxacor 86Glyphosate Atrazine + (S)-metolachlor + mesotrione + bicyclopyrone +benoxacor 87 Glyphosate Tembotrione + isoxadifen-ethyl 88 GlyphosateTembotrione + thiencarbazone-methyl + isoxadifen-ethyl 89 GlyphosateIsoxaflutole + cyprosulfamide 90 Glyphosate Isoxaflutole +thiencarbazone-methyl + cyprosulfamide 91 Glyphosate Acetochlor +flumetsulam + clopyralid 92 Glyphosate Saflufenacil + dimethenamid-P 93Glyphosate Atrazine dimethylammonium 94 Glyphosate Acetochlordimethylammonium 95 Glyphosate Metolachlor dimethylammonium 96Glyphosate (S)-Metolachlor dimethylammonium 97 Glyphosate Dimethenamiddimethylammonium 98 Glyphosate Dimethenamid-P dimethylammonium 99Glyphosate Pyroxasulfone dimethylammonium 100 GlyphosateThiencarbazone-methyl dimethylammonium 101 Glyphosate Flumetsulamdimethylammonium 102 Glyphosate Trifludimoxazin dimethylammonium 103Glyphosate Saflufenacil dimethylammonium 104 Glyphosate Isoxaflutoledimethylammonium 105 Glyphosate Bicyclopyrone dimethylammonium 106Glyphosate Tembotrione dimethylammonium 107 Glyphosate Mesotrionedimethylammonium 108 Glyphosate Atrazine + (S)-metolachlor + benoxacordimethylammonium 109 Glyphosate Atrazine + (S)-metolachlor +mesotrione + dimethylammonium bicyclopyrone + benoxacor 110 GlyphosateTembotrione + isoxadifen-ethyl dimethylammonium 111 GlyphosateTembotrione + thiencarbazone-methyl + dimethylammonium isoxadifen-ethyl112 Glyphosate Isoxaflutole + cyprosulfamide dimethylammonium 113Glyphosate Isoxaflutole + thiencarbazone-methyl + dimethylammoniumcyprosulfamide 114 Glyphosate Acetochlor + flumetsulam + clopyraliddimethylammonium 115 Glyphosate Saflufenacil + dimethenamid-Pdimethylammonium 116 Glyphosate potassium Atrazine 117 Glyphosatepotassium Acetochlor 118 Glyphosate potassium Metolachlor 119 Glyphosatepotassium (S)-Metolachlor 120 Glyphosate potassium Dimethenamid 121Glyphosate potassium Dimethenamid-P 122 Glyphosate potassiumPyroxasulfone 123 Glyphosate potassium Thiencarbazone-methyl 124Glyphosate potassium Flumetsulam 125 Glyphosate potassiumTrifludimoxazin 126 Glyphosate potassium Saflufenacil 127 Glyphosatepotassium Isoxaflutole 128 Glyphosate potassium Bicyclopyrone 129Glyphosate potassium Tembotrione 130 Glyphosate potassium Mesotrione 131Glyphosate potassium Atrazine + (S)-metolachlor + benoxacor 132Glyphosate potassium Atrazine + (S)-metolachlor + mesotrione +bicyclopyrone + benoxacor 133 Glyphosate potassium Tembotrione +isoxadifen-ethyl 134 Glyphosate potassium Tembotrione +thiencarbazone-methyl + isoxadifen-ethyl 135 Glyphosate potassiumIsoxaflutole + cyprosulfamide 136 Glyphosate potassium Isoxaflutole +thiencarbazone-methyl + cyprosulfamide 137 Glyphosate potassiumAcetochlor + flumetsulam + clopyralid 138 Glyphosate potassiumSaflufenacil + dimethenamid-P 139 Glyphosate Atrazine isopropylammonium140 Glyphosate Acetochlor isopropylammonium 141 Glyphosate Metolachlorisopropylammonium 142 Glyphosate (S)-Metolachlor isopropylammonium 143Glyphosate Dimethenamid isopropylammonium 144 Glyphosate Dimethenamid-Pisopropylammonium 145 Glyphosate Pyroxasulfone isopropylammonium 146Glyphosate Thiencarbazone-methyl isopropylammonium 147 GlyphosateFlumetsulam isopropylammonium 148 Glyphosate Trifludimoxazinisopropylammonium 149 Glyphosate Saflufenacil isopropylammonium 150Glyphosate Isoxaflutole isopropylammonium 151 Glyphosate Bicyclopyroneisopropylammonium 152 Glyphosate Tembotrione isopropylammonium 153Glyphosate Mesotrione isopropylammonium 154 Glyphosate Atrazine +(S)-metolachlor + benoxacor isopropylammonium 155 Glyphosate Atrazine +(S)-metolachlor + mesotrione + isopropylammonium bicyclopyrone +benoxacor 156 Glyphosate Tembotrione + isoxadifen-ethylisopropylammonium 157 Glyphosate Tembotrione + thiencarbazone-methyl +isopropylammonium isoxadifen-ethyl 158 Glyphosate Isoxaflutole +cyprosulfamide isopropylammonium 159 Glyphosate Isoxaflutole +thiencarbazone-methyl + isopropylammonium cyprosulfamide 160 GlyphosateAcetochlor + flumetsulam + clopyralid isopropylammonium 161 GlyphosateSaflufenacil + dimethenamid-P isopropylammonium 162 SaflufenacilAtrazine 163 Saflufenacil Acetochlor 164 Saflufenacil Metolachlor 165Saflufenacil (S)-Metolachlor 166 Saflufenacil Dimethenamid 167Saflufenacil Dimethenamid-P 168 Saflufenacil Pyroxasulfone 169Saflufenacil Thiencarbazone-methyl 170 Saflufenacil Flumetsulam 171Saflufenacil Trifludimoxazin 172 Saflufenacil Saflufenacil 173Saflufenacil Isoxaflutole 174 Saflufenacil Bicyclopyrone 175Saflufenacil Tembotrione 176 Saflufenacil Mesotrione 177 SaflufenacilAtrazine + (S)-metolachlor + benoxacor 178 Saflufenacil Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 179Saflufenacil Tembotrione + isoxadifen-ethyl 180 SaflufenacilTembotrione + thiencarbazone-methyl + isoxadifen-ethyl 181 SaflufenacilIsoxaflutole + cyprosulfamide 182 Saflufenacil Isoxaflutole +thiencarbazone-methyl + cyprosulfamide 183 Saflufenacil Acetochlor +flumetsulam + clopyralid 184 Saflufenacil Saflufenacil + dimethenamid-P185 Trifludimoxazin Atrazine 186 Trifludimoxazin Acetochlor 187Trifludimoxazin Metolachlor 188 Trifludimoxazin (S)-Metolachlor 189Trifludimoxazin Dimethenamid 190 Trifludimoxazin Dimethenamid-P 191Trifludimoxazin Pyroxasulfone 192 Trifludimoxazin Thiencarbazone-methyl193 Trifludimoxazin Flumetsulam 194 Trifludimoxazin Trifludimoxazin 195Trifludimoxazin Saflufenacil 196 Trifludimoxazin Isoxaflutole 197Trifludimoxazin Bicyclopyrone 198 Trifludimoxazin Tembotrione 199Trifludimoxazin Mesotrione 200 Trifludimoxazin Atrazine +(S)-metolachlor + benoxacor 201 Trifludimoxazin Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 202Trifludimoxazin Tembotrione + isoxadifen-ethyl 203 TrifludimoxazinTembotrione + thiencarbazone-methyl + isoxadifen-ethyl 204Trifludimoxazin Isoxaflutole + cyprosulfamide 205 TrifludimoxazinIsoxaflutole + thiencarbazone-methyl + cyprosulfamide 206Trifludimoxazin Acetochlor + flumetsulam + clopyralid 207Trifludimoxazin Saflufenacil + dimethenamid-P 208 Saflufenacil +Atrazine trifludimoxazin 209 Saflufenacil + Acetochlor trifludimoxazin210 Saflufenacil + Metolachlor trifludimoxazin 211 Saflufenacil +(S)-Metolachlor trifludimoxazin 212 Saflufenacil + Dimethenamidtrifludimoxazin 213 Saflufenacil + Dimethenamid-P trifludimoxazin 214Saflufenacil + Pyroxasulfone trifludimoxazin 215 Saflufenacil +Thiencarbazone-methyl trifludimoxazin 216 Saflufenacil + Flumetsulamtrifludimoxazin 217 Saflufenacil + Trifludimoxazin trifludimoxazin 218Saflufenacil + Saflufenacil trifludimoxazin 219 Saflufenacil +Isoxaflutole trifludimoxazin 220 Saflufenacil + Bicyclopyronetrifludimoxazin 221 Saflufenacil + Tembotrione trifludimoxazin 222Saflufenacil + Mesotrione trifludimoxazin 223 Saflufenacil + Atrazine +(S)-metolachlor + benoxacor trifludimoxazin 224 Saflufenacil +Atrazine + (S)-metolachlor + mesotrione + trifludimoxazinbicyclopyrone + benoxacor 225 Saflufenacil + Tembotrione +isoxadifen-ethyl trifludimoxazin 226 Saflufenacil + Tembotrione +thiencarbazone-methyl + trifludimoxazin isoxadifen-ethyl 227Saflufenacil + Isoxaflutole + cyprosulfamide trifludimoxazin 228Saflufenacil + Isoxaflutole + thiencarbazone-methyl + trifludimoxazincyprosulfamide 229 Saflufenacil + Acetochlor + flumetsulam + clopyralidtrifludimoxazin 230 Saflufenacil + Saflufenacil + dimethenamid-Ptrifludimoxazin 231 Dicamba Atrazine 232 Dicamba Acetochlor 233 DicambaMetolachlor 234 Dicamba (S)-Metolachlor 235 Dicamba Dimethenamid 236Dicamba Dimethenamid-P 237 Dicamba Pyroxasulfone 238 DicambaThiencarbazone-methyl 239 Dicamba Flumetsulam 240 DicambaTrifludimoxazin 241 Dicamba Saflufenacil 242 Dicamba Isoxaflutole 243Dicamba Bicyclopyrone 244 Dicamba Tembotrione 245 Dicamba Mesotrione 246Dicamba Atrazine + (S)-metolachlor + benoxacor 247 Dicamba Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 248 DicambaTembotrione + isoxadifen-ethyl 249 Dicamba Tembotrione +thiencarbazone-methyl + isoxadifen-ethyl 250 Dicamba Isoxaflutole +cyprosulfamide 251 Dicamba Isoxaflutole + thiencarbazone-methyl +cyprosulfamide 252 Dicamba Acetochlor + flumetsulam + clopyralid 253Dicamba Saflufenacil + dimethenamid-P 254 Dicamba ethanolamine saltAtrazine 255 Dicamba ethanolamine salt Acetochlor 256 Dicambaethanolamine salt Metolachlor 257 Dicamba ethanolamine salt(S)-Metolachlor 258 Dicamba ethanolamine salt Dimethenamid 259 Dicambaethanolamine salt Dimethenamid-P 260 Dicamba ethanolamine saltPyroxasulfone 261 Dicamba ethanolamine salt Thiencarbazone-methyl 262Dicamba ethanolamine salt Flumetsulam 263 Dicamba ethanolamine saltTrifludimoxazin 264 Dicamba ethanolamine salt Saflufenacil 265 Dicambaethanolamine salt Isoxaflutole 266 Dicamba ethanolamine saltBicyclopyrone 267 Dicamba ethanolamine salt Tembotrione 268 Dicambaethanolamine salt Mesotrione 269 Dicamba ethanolamine salt Atrazine +(S)-metolachlor + benoxacor 270 Dicamba ethanolamine salt Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 271 Dicambaethanolamine salt Tembotrione + isoxadifen-ethyl 272 Dicambaethanolamine salt Tembotrione + thiencarbazone-methyl + isoxadifen-ethyl273 Dicamba ethanolamine salt Isoxaflutole + cyprosulfamide 274 Dicambaethanolamine salt Isoxaflutole + thiencarbazone-methyl + cyprosulfamide275 Dicamba ethanolamine salt Acetochlor + flumetsulam + clopyralid 276Dicamba ethanolamine salt Saflufenacil + dimethenamid-P 277 Dicambadiglycolamine salt Atrazine 278 Dicamba diglycolamine salt Acetochlor279 Dicamba diglycolamine salt Metolachlor 280 Dicamba diglycolaminesalt (S)-Metolachlor 281 Dicamba diglycolamine salt Dimethenamid 282Dicamba diglycolamine salt Dimethenamid-P 283 Dicamba diglycolamine saltPyroxasulfone 284 Dicamba diglycolamine salt Thiencarbazone-methyl 285Dicamba diglycolamine salt Flumetsulam 286 Dicamba diglycolamine saltTrifludimoxazin 287 Dicamba diglycolamine salt Saflufenacil 288 Dicambadiglycolamine salt Isoxaflutole 289 Dicamba diglycolamine saltBicyclopyrone 290 Dicamba diglycolamine salt Tembotrione 291 Dicambadiglycolamine salt Mesotrione 292 Dicamba diglycolamine salt Atrazine +(S)-metolachlor + benoxacor 293 Dicamba diglycolamine salt Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 294 Dicambadiglycolamine salt Tembotrione + isoxadifen-ethyl 295 Dicambadiglycolamine salt Tembotrione + thiencarbazone-methyl +isoxadifen-ethyl 296 Dicamba diglycolamine salt Isoxaflutole +cyprosulfamide 297 Dicamba diglycolamine salt Isoxaflutole +thiencarbazone-methyl + cyprosulfamide 298 Dicamba diglycolamine saltAcetochlor + flumetsulam + clopyralid 299 Dicamba diglycolamine saltSaflufenacil + dimethenamid-P 300 Dicamba potassium Atrazine 301 Dicambapotassium Acetochlor 302 Dicamba potassium Metolachlor 303 Dicambapotassium (S)-Metolachlor 304 Dicamba potassium Dimethenamid 305 Dicambapotassium Dimethenamid-P 306 Dicamba potassium Pyroxasulfone 307 Dicambapotassium Thiencarbazone-methyl 308 Dicamba potassium Flumetsulam 309Dicamba potassium Trifludimoxazin 310 Dicamba potassium Saflufenacil 311Dicamba potassium Isoxaflutole 312 Dicamba potassium Bicyclopyrone 313Dicamba potassium Tembotrione 314 Dicamba potassium Mesotrione 315Dicamba potassium Atrazine + (S)-metolachlor + benoxacor 316 Dicambapotassium Atrazine + (S)-metolachlor + mesotrione + bicyclopyrone +benoxacor 317 Dicamba potassium Tembotrione + isoxadifen-ethyl 318Dicamba potassium Tembotrione + thiencarbazone-methyl + isoxadifen-ethyl319 Dicamba potassium Isoxaflutole + cyprosulfamide 320 Dicambapotassium Isoxaflutole + thiencarbazone-methyl + cyprosulfamide 321Dicamba potassium Acetochlor + flumetsulam + clopyralid 322 Dicambapotassium Saflufenacil + dimethenamid-P 323 Dicamba BAPMA salt Atrazine324 Dicamba BAPMA salt Acetochlor 325 Dicamba BAPMA salt Metolachlor 326Dicamba BAPMA salt (S)-Metolachlor 327 Dicamba BAPMA salt Dimethenamid328 Dicamba BAPMA salt Dimethenamid-P 329 Dicamba BAPMA saltPyroxasulfone 330 Dicamba BAPMA salt Thiencarbazone-methyl 331 DicambaBAPMA salt Flumetsulam 332 Dicamba BAPMA salt Trifludimoxazin 333Dicamba BAPMA salt Saflufenacil 334 Dicamba BAPMA salt Isoxaflutole 335Dicamba BAPMA salt Bicyclopyrone 336 Dicamba BAPMA salt Tembotrione 337Dicamba BAPMA salt Mesotrione 338 Dicamba BAPMA salt Atrazine +(S)-metolachlor + benoxacor 339 Dicamba BAPMA salt Atrazine +(S)-metolachlor + mesotrione + bicyclopyrone + benoxacor 340 DicambaBAPMA salt Tembotrione + isoxadifen-ethyl 341 Dicamba BAPMA saltTembotrione + thiencarbazone-methyl + isoxadifen-ethyl 342 Dicamba BAPMAsalt Isoxaflutole + cyprosulfamide 343 Dicamba BAPMA salt Isoxaflutole +thiencarbazone-methyl + cyprosulfamide 344 Dicamba BAPMA saltAcetochlor + flumetsulam + clopyralid 345 Dicamba BAPMA saltSaflufenacil + dimethenamid-P 346 — Atrazine 347 — Acetochlor 348 —Metolachlor 349 — (S)-Metolachlor 350 — Dimethenamid 351 —Dimethenamid-P 352 — Pyroxasulfone 353 — Thiencarbazone-methyl 354 —Flumetsulam 355 — Trifludimoxazin 356 — Saflufenacil 357 — Isoxaflutole358 — Bicyclopyrone 359 — Tembotrione 360 — Mesotrione 361 — Atrazine +(S)-metolachlor + benoxacor 362 — Atrazine + (S)-metolachlor +mesotrione + bicyclopyrone + benoxacor 363 — Tembotrione +isoxadifen-ethyl 364 — Tembotrione + thiencarbazone-methyl +isoxadifen-ethyl 365 — Isoxaflutole + cyprosulfamide 366 —Isoxaflutole + thiencarbazone-methyl + cyprosulfamide 367 — Acetochlor +flumetsulam + clopyralid 368 — Saflufenacil + dimethenamid-P 369L-Glufosinate — 370 L-Glufosinate ammonium — 371 L-Glufosinate sodium —372 Glyphosate — 373 Glyphosate — dimethylammonium 374 Glyphosatepotassium — 375 Glyphosate — isopropylammonium 376 Saflufenacil — 377Trifludimoxazin — 378 Saflufenacil + — trifludimoxazin 379 Dicamba — 380Dicamba ethanolamine salt — 381 Dicamba diglycolamine salt — 382 Dicambapotassium — 383 Dicamba BAPMA salt —

The treatment combinations 2.1 to 2.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium.

The treatment combinations 3.1 to 3.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium.

The treatment combinations 4.1 to 4.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and atrazine.

The treatment combinations 5.1 to 5.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and atrazine.

The treatment combinations 6.1 to 6.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and atrazine.

The treatment combinations 7.1 to 7.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and topramezone.

The treatment combinations 8.1 to 8.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and topramezone.

The treatment combinations 9.1 to 9.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and topramezone.

The treatment combinations 10.1 to 10.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and dicamba.

The treatment combinations 11.1 to 11.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and dicamba ethanolamine salt.

The treatment combinations 12.1 to 12.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and dicamba diglycolamine salt.

The treatment combinations 13.1 to 13.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and dicamba potassium.

The treatment combinations 14.1 to 14.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and dicamba BAPMA salt.

The treatment combinations 15.1 to 15.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and dicamba.

The treatment combinations 16.1 to 16.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and dicamba ethanolaminesalt.

The treatment combinations 17.1 to 17.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and dicamba diglycolaminesalt.

The treatment combinations 18.1 to 18.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and dicamba potassium.

The treatment combinations 19.1 to 19.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and dicamba BAPMA salt.

The treatment combinations 20.1 to 20.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and dicamba.

The treatment combinations 21.1 to 21.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and dicamba ethanolaminesalt.

The treatment combinations 22.1 to 22.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and dicamba diglycolaminesalt.

The treatment combinations 23.1 to 23.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and dicamba potassium.

The treatment combinations 24.1 to 24.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and dicamba BAPMA salt.

The treatment combinations 25.1 to 25.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate and dicamba.

The treatment combinations 26.1 to 26.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate and dicamba ethanolaminesalt.

The treatment combinations 27.1 to 27.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate and dicambadiglycolamine salt.

The treatment combinations 28.1 to 28.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate and dicamba potassium.

The treatment combinations 29.1 to 29.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate and dicamba BAPMA salt.

The treatment combinations 30.1 to 30.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate and dicamba.

The treatment combinations 31.1 to 31.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate and dicambaethanolamine salt.

The treatment combinations 32.1 to 32.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate and dicambadiglycolamine salt.

The treatment combinations 33.1 to 33.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate and dicambapotassium.

The treatment combinations 34.1 to 34.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate and dicambaBAPMA salt.

The treatment combinations 35.1 to 35.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate and dicamba.

The treatment combinations 36.1 to 36.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate and dicambaethanolamine salt.

The treatment combinations 37.1 to 37.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate and dicambadiglycolamine salt.

The treatment combinations 38.1 to 38.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate and dicambapotassium.

The treatment combinations 39.1 to 39.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate and dicamba BAPMAsalt.

The treatment combinations 40.1 to 40.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate dimethylammonium anddicamba.

The treatment combinations 41.1 to 41.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate dimethylammonium anddicamba ethanolamine salt.

The treatment combinations 42.1 to 42.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate dimethylammonium anddicamba diglycolamine salt.

The treatment combinations 43.1 to 43.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate dimethylammonium anddicamba potassium.

The treatment combinations 44.1 to 44.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate dimethylammonium anddicamba BAPMA salt.

The treatment combinations 45.1 to 45.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosatedimethylammonium and dicamba.

The treatment combinations 46.1 to 46.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosatedimethylammonium and dicamba ethanolamine salt.

The treatment combinations 47.1 to 47.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosatedimethylammonium and dicamba diglycolamine salt.

The treatment combinations 48.1 to 48.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosatedimethylammonium and dicamba potassium.

The treatment combinations 49.1 to 49.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosatedimethylammonium and dicamba BAPMA salt.

The treatment combinations 50.1 to 50.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate dimethylammoniumand dicamba.

The treatment combinations 51.1 to 51.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate dimethylammoniumand dicamba ethanolamine salt.

The treatment combinations 52.1 to 52.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate dimethylammoniumand dicamba diglycolamine salt.

The treatment combinations 53.1 to 53.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate dimethylammoniumand dicamba potassium.

The treatment combinations 54.1 to 54.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate dimethylammoniumand dicamba BAPMA salt.

The treatment combinations 55.1 to 55.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate potassium and dicamba.

The treatment combinations 56.1 to 56.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate potassium and dicambaethanolamine salt.

The treatment combinations 57.1 to 57.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate potassium and dicambadiglycolamine salt.

The treatment combinations 58.1 to 58.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate potassium and dicambapotassium.

The treatment combinations 59.1 to 59.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate potassium and dicambaBAPMA salt.

The treatment combinations 60.1 to 60.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate potassium anddicamba.

The treatment combinations 61.1 to 61.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate potassium anddicamba ethanolamine salt.

The treatment combinations 62.1 to 62.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate potassium anddicamba diglycolamine salt.

The treatment combinations 63.1 to 63.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate potassium anddicamba potassium.

The treatment combinations 64.1 to 64.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosate potassium anddicamba BAPMA salt.

The treatment combinations 65.1 to 65.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate potassium anddicamba.

The treatment combinations 66.1 to 66.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate potassium anddicamba ethanolamine salt.

The treatment combinations 67.1 to 67.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate potassium anddicamba diglycolamine salt.

The treatment combinations 68.1 to 68.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate potassium anddicamba potassium.

The treatment combinations 69.1 to 69.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate potassium anddicamba BAPMA salt.

The treatment combinations 70.1 to 70.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate iso-propylammonium anddicamba.

The treatment combinations 71.1 to 71.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate iso-propylammonium anddicamba ethanolamine salt.

The treatment combinations 72.1 to 72.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate iso-propylammonium anddicamba diglycolamine salt.

The treatment combinations 73.1 to 73.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate iso-propylammonium anddicamba potassium.

The treatment combinations 74.1 to 74.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, glyphosate iso-propylammonium anddicamba BAPMA salt.

The treatment combinations 75.1 to 75.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosateisopropylammonium and dicamba.

The treatment combinations 76.1 to 76.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosateisopropylammonium and dicamba ethanolamine salt.

The treatment combinations 77.1 to 77.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosateisopropylammonium and dicamba diglycolamine salt.

The treatment combinations 78.1 to 78.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosateisopropylammonium and dicamba potassium.

The treatment combinations 79.1 to 79.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, glyphosateisopropylammonium and dicamba BAPMA salt.

The treatment combinations 80.1 to 80.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate isopropylammoniumand dicamba.

The treatment combinations 81.1 to 81.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate isopropylammoniumand dicamba ethanolamine salt.

The treatment combinations 82.1 to 82.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate isopropylammoniumand dicamba diglycolamine salt.

The treatment combinations 83.1 to 83.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate isopropylammoniumand dicamba potassium.

The treatment combinations 84.1 to 84.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, glyphosate isopropylammoniumand dicamba BAPMA salt.

The treatment combinations 85.1 to 85.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate.

The treatment combinations 86.1 to 86.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate and dicamba.

The treatment combinations 87.1 to 87.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate and dicamba ethanolamine salt.

The treatment combinations 88.1 to 88.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate and dicamba diglycolamine salt.

The treatment combinations 89.1 to 89.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate and dicamba potassium.

The treatment combinations 90.1 to 90.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate and dicamba BAPMA salt.

The treatment combinations 91.1 to 91.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium.

The treatment combinations 92.1 to 92.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and dicamba.

The treatment combinations 93.1 to 93.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and dicamba ethanolaminesalt.

The treatment combinations 94.1 to 94.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and dicamba diglycolaminesalt.

The treatment combinations 95.1 to 95.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and dicamba potassium.

The treatment combinations 96.1 to 96.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and dicamba BAPMA salt.

The treatment combinations 97.1 to 97.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium.

The treatment combinations 98.1 to 98.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and dicamba.

The treatment combinations 99.1 to 99.383 in which one of the treatmentcombinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and dicambaethanolamine salt.

The treatment combinations 100.1 to 100.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and dicambadiglycolamine salt.

The treatment combinations 101.1 to 101.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and dicambapotassium.

The treatment combinations 102.1 to 102.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and dicamba BAPMAsalt.

The treatment combinations 103.1 to 103.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and 2,4-D.

The treatment combinations 104.1 to 104.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and 2,4-D choline salt.

The treatment combinations 105.1 to 105.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and 2,4-D.

The treatment combinations 106.1 to 106.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and 2,4-D choline salt.

The treatment combinations 107.1 to 107.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and 2,4-D.

The treatment combinations 108.1 to 108.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and 2,4-D choline salt.

The treatment combinations 109.1 to 109.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, topramezone and dimethenamid-P.

The treatment combinations 110.1 to 110.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, topramezone anddimethenamid-P.

The treatment combinations 111.1 to 111.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, topramezone anddimethenamid-P.

The treatment combinations 112.1 to 112.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and isoxaflutole.

The treatment combinations 113.1 to 113.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and isoxaflutole.

The treatment combinations 114.1 to 114.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and isoxaflutole.

The treatment combinations 115.1 to 115.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, isoxaflutole, thiencarbazone-methyland isoxadifen-ethyl.

The treatment combinations 116.1 to 116.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, isoxaflutole,thiencarbazone-methyl and isoxadifen-ethyl.

The treatment combinations 117.1 to 117.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, isoxaflutole,thiencarbazone-methyl and isoxadifen-ethyl.

The treatment combinations 118.1 to 118.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and mesotrione.

The treatment combinations 119.1 to 119.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and meostrione.

The treatment combinations 120.1 to 120.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and mesotrione.

The treatment combinations 121.1 to 121.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, atrazine and mesotrione.

The treatment combinations 122.1 to 122.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and mesotrione.

The treatment combinations 123.1 to 123.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, atrazine and mesotrione.

The treatment combinations 124.1 to 124.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, tembotrione and isoxadifen-ethyl.

The treatment combinations 125.1 to 125.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, tembotrione andisoxadifen-ethyl.

The treatment combinations 126.1 to 126.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, tembotrione andisoxadifen-ethyl.

The treatment combinations 127.1 to 127.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, tembotrione, thiencarbazone-methyland isoxadifen-ethyl.

The treatment combinations 128.1 to 128.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, tembotrione,thiencarbazone-methyl and isoxadifen-ethyl.

The treatment combinations 129.1 to 129.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, tembotrione,thiencarbazone-methyl and isoxadifen-ethyl.

The treatment combinations 130.1 to 130.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and bicyclopyrone.

The treatment combinations 131.1 to 131.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and bicyclopyrone.

The treatment combinations 132.1 to 132.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and bicyclopyrone.

The treatment combinations 133.1 to 133.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, dicamba sodium and diflufenzopyrsodium.

The treatment combinations 134.1 to 134.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, dicamba sodium anddiflufenzopyr sodium.

The treatment combinations 135.1 to 135.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, dicamba sodium anddiflufenzopyr sodium.

The treatment combinations 136.1 to 136.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate, dicamba sodium, diflufenzopyrsodium and isoxadifen-ethyl.

The treatment combinations 137.1 to 137.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium, dicamba sodium,diflufenzopyr sodium and isoxadifen-ethyl.

The treatment combinations 138.1 to 138.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium, dicamba sodium,diflufenzopyr sodium and isoxadifen-ethyl.

The treatment combinations 139.1 to 139.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba.

The treatment combinations 140.1 to 140.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt.

The treatment combinations 141.1 to 141.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt.

The treatment combinations 142.1 to 142.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium.

The treatment combinations 143.1 to 143.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt.

The treatment combinations 144.1 to 144.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of 2,4-D.

The treatment combinations 145.1 to 145.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of 2,4-D choline salt.

The treatment combinations 146.1 to 146.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of atrazine.

The treatment combinations 147.1 to 147.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of topramezone.

The treatment combinations 148.1 to 148.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of topramezone and dimethenamid-P.

The treatment combinations 149.1 to 149.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of topramezone and atrazine.

The treatment combinations 150.1 to 150.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of isoxaflutole.

The treatment combinations 151.1 to 151.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of isoxaflutole, thiencarbazone-methyl andisoxadifen-ethyl.

The treatment combinations 152.1 to 152.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of mesotrione.

The treatment combinations 153.1 to 153.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of atrazine and mesotrione.

The treatment combinations 154.1 to 154.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of tembotrione and isoxadifenethyl.

The treatment combinations 155.1 to 155.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of tembotrione, thiencarbazone-methyl andisoxadifen-ethyl.

The treatment combinations 156.1 to 156.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of bicyclopyrone.

The treatment combinations 157.1 to 157.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba sodium and diflufenzopyr sodium.

The treatment combinations 158.1 to 158.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba sodium, diflufenzopyr sodium andisoxadifen-ethyl.

The treatment combinations 159.1 to 159.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate and tiafenacil.

The treatment combinations 160.1 to 160.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate ammonium and tiafenacil.

The treatment combinations 161.1 to 161.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of L-glufosinate sodium and tiafenacil.

The treatment combinations 162.1 to 162.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and tiafenacil.

The treatment combinations 163.1 to 163.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and tiafenacil.

The treatment combinations 164.1 to 164.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and tiafenacil.

The treatment combinations 165.1 to 165.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and tiafenacil.

The treatment combinations 166.1 to 166.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and tiafenacil.

The treatment combinations 167.1 to 167.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and tiafenacil.

The treatment combinations 168.1 to 168.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and tiafenacil.

The treatment combinations 169.1 to 169.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and tiafenacil.

The treatment combinations 170.1 to 170.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and tiafenacil.

The treatment combinations 171.1 to 171.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of tiafenacil.

The treatment combinations 172.1 to 172.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and trifludimoxazin.

The treatment combinations 173.1 to 173.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and trifludimoxazin.

The treatment combinations 174.1 to 174.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and trifludimoxazin.

The treatment combinations 175.1 to 175.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and trifludimoxazin.

The treatment combinations 176.1 to 176.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and trifludimoxazin.

The treatment combinations 177.1 to 177.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and trifludimoxazin.

The treatment combinations 178.1 to 178.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and trifludimoxazin.

The treatment combinations 179.1 to 179.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and trifludimoxazin.

The treatment combinations 180.1 to 180.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and trifludimoxazin.

The treatment combinations 181.1 to 181.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of trifludimoxazin.

The treatment combinations 182.1 to 182.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and saflufenacil.

The treatment combinations 183.1 to 183.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and saflufenacil.

The treatment combinations 184.1 to 184.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and saflufenacil.

The treatment combinations 185.1 to 185.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and saflufenacil.

The treatment combinations 186.1 to 186.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and saflufenacil.

The treatment combinations 187.1 to 187.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and saflufenacil.

The treatment combinations 188.1 to 188.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and saflufenacil.

The treatment combinations 189.1 to 189.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and saflufenacil.

The treatment combinations 190.1 to 190.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and saflufenacil.

The treatment combinations 191.1 to 191.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of saflufenacil.

The treatment combinations 192.1 to 192.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and saflufenacil and trifludimoxazin.

The treatment combinations 193.1 to 193.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and saflufenacil andtrifludimoxazin.

The treatment combinations 194.1 to 194.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and saflufenacil andtrifludimoxazin.

The treatment combinations 195.1 to 195.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and saflufenacil andtrifludimoxazin.

The treatment combinations 196.1 to 196.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and saflufenacil and trifludimoxazin.

The treatment combinations 197.1 to 197.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and saflufenacil.

The treatment combinations 136.1 to 136.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and saflufenacil andtrifludimoxazin.

The treatment combinations 198.1 to 198.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and saflufenacil andtrifludimoxazin.

The treatment combinations 199.1 to 199.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and saflufenacil andtrifludimoxazin.

The treatment combinations 200.1 to 200.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of saflufenacil and trifludimoxazin.

The treatment combinations 201.1 to 201.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and sulfentrazone.

The treatment combinations 202.1 to 202.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and sulfentrazone.

The treatment combinations 203.1 to 203.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and sulfentrazone.

The treatment combinations 204.1 to 204.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and sulfentrazone.

The treatment combinations 205.1 to 205.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and sulfentrazone.

The treatment combinations 206.1 to 206.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and sulfentrazone.

The treatment combinations 207.1 to 207.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and sulfentrazone.

The treatment combinations 208.1 to 208.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and sulfentrazone.

The treatment combinations 209.1 to 209.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and sulfentrazone.

The treatment combinations 210.1 to 210.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of sulfentrazone.

The treatment combinations 211.1 to 211.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and flumioxazin.

The treatment combinations 212.1 to 212.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and flumioxazin.

The treatment combinations 213.1 to 213.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and flumioxazin.

The treatment combinations 214.1 to 214.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and flumioxazin.

The treatment combinations 215.1 to 215.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and flumioxazin.

The treatment combinations 216.1 to 216.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and flumioxazin.

The treatment combinations 217.1 to 217.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and flumioxazin.

The treatment combinations 218.1 to 218.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and flumioxazin.

The treatment combinations 219.1 to 219.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and flumioxazin.

The treatment combinations 220.1 to 220.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of flumioxazin.

The treatment combinations 221.1 to 221.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and carfentrazone-ethyl.

The treatment combinations 222.1 to 222.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium andcarfentrazone-ethyl.

The treatment combinations 223.1 to 223.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and carfentrazone-ethyl.

The treatment combinations 224.1 to 224.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium andcarfentrazone-ethyl.

The treatment combinations 225.1 to 225.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and carfentrazone-ethyl.

The treatment combinations 226.1 to 226.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and carfentrazone-ethyl.

The treatment combinations 227.1 to 227.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt andcarfentrazone-ethyl.

The treatment combinations 228.1 to 228.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and carfentrazone-ethyl.

The treatment combinations 229.1 to 229.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and carfentrazone-ethyl.

The treatment combinations 230.1 to 230.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of carfentrazone-ethyl.

The treatment combinations 231.1 to 231.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 232.1 to 232.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate dimethylammonium and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 233.1 to 233.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate potassium and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 234.1 to 234.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of glyphosate isopropylammonium and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 235.1 to 235.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 236.1 to 236.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba ethanolamine salt and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 237.1 to 237.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba diglycolamine salt and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 238.1 to 238.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba potassium and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 239.1 to 239.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of dicamba BAPMA salt and II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The treatment combinations 240.1 to 240.383 in which one of thetreatment combinations listed in the preceeding table is combined withpost-emergence use of II-83: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate.

The abovementioned properties and advantages are necessary underpractical weed control conditions to keep the corn free from undesiredcompeting plants and thus to guarantee and/or increase the yields fromthe qualitative and quantitative point of view. These novel combinationsmarkedly exceed the technical state of the art with a view to theproperties described.

While the active compounds of the inventive mixtures have an outstandingherbicidal activity against monocotyledonous and dicotyledonous weeds,the tolerant, or cross-tolerant, glufosinate tolerant corn are damagedonly to a minor extent, or not at all.

As mentioned above, the inventive mixtures are suitable for controllinga large number of harmful plants in glufosinate tolerant corn

Thus, the term “ glufosinate tolerant corn” as used herein includes also(corn) plants which have been modified by mutagenesis, geneticengineering or breeding and mutation selection techniques in order toprovide a new trait to a plant or to modify an already present trait.

Mutagenesis includes techniques of random mutagenesis using X-rays ormutagenic chemicals, but also techniques of targeted mutagenesis, inorder to create mutations at a specific locus of a plant genome.Targeted mutagenesis techniques frequently use oligonucleotides orproteins like CRISPR/Cas, zinc-finger nucleases, TALENs or meganucleasesto achieve the targeting effect.

Genetic engineering usually uses recombinant DNA techniques to createmodifications in a plant genome which under natural circumstances cannotreadily be obtained by cross breeding, mutagenesis or naturalrecombination. Typically, one or more genes are integrated into thegenome of a plant in order to add a trait or improve a trait. Theseintegrated genes are also referred to as transgenes in the art, whileplant comprising such transgenes are referred to as transgenic plants.The process of plant transformation usually produces severaltransformation events, wich differ in the genomic locus in which atransgene has been integrated. Plants comprising a specific transgene ona specific genomic locus are usually described as comprising a specific“event”, which is referred to by a specific event name.

Glufosinate tolerance has been created by using mutagenesis as well asusing genetic engineering.

Transgenic corn events comprising glufosinate tolerance genes are forexample, but not excluding others, 5307×MIR604×Bt11×TC1507×GA21×MIR162(event code:SYN-Ø53Ø7-1×SYN-IR6Ø4-5×SYN-BTØ11-1×DAS-Ø15Ø7-1×MON-ØØØ21-9×SYN-IR162-4,gene: pat, e.g. commercially available as Agrisure® Duracade™ 5222),59122 (event code: DAS-59122-7, gene: pat, e.g. commercially availableas Herculex™ RW), 5307×MIR604×Bt11×TC1507×GA21 (event code:SYN-Ø53Ø7-1×SYN-IR6Ø4-5×SYN-BTØ11-1×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat,e.g. commercially available as Agrisure® Duracade™ 5122), 59122×NK603(event code: DAS-59122-7×MON-ØØ6Ø3-6, gene: pat, e.g. commerciallyavailable as Herculex™ RW Roundup Ready™ 2), Bt10 (gene: pat, e.g.commercially available as Bt10), Bt11 (X4334CBR, X4734CBR) (event code:SYN-BTØ11-1, gene: pat, e.g. commercially available as Agrisure™ CB/LL),BT11×59122×MIR604×TC1507×GA21 (event code:SYN-BTØ11-1×DAS-59122-7×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat,e.g. commercially available as Agrisure® 3122), Bt11×GA21 (event code:SYN-BTØ11-1×MON-ØØØ21-9, gene: pat, e.g. commercially available asAgrisureTM GT/CB/LL), Bt11×MIR162 (event code: SYN-BTØ11-1×SYN-IR162-4,gene: pat, e.g. commercially available as Agrisure® Viptera™ 2100),Bt11×MIR162×GA21 (event code: SYN-BTØ11-1×SYN-IR162-4×MON-ØØØ21-9, gene:pat, e.g. commercially available as Agrisure® Viptera™ 3110),BT11×MIR162×MIR604 (event code: SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5,gene: pat, e.g. commercially available as Agrisure® Viptera™ 3100),Bt11×MIR162×MIR604×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×MON-ØØØ21-9, gene: pat, e.g.commercially available as Agrisure® Viptera™ 3111, Agrisure® Viptera™4), Bt11×MIR162×TC1507×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat, e.g.commercially available as Agrisure™ Viptera 3220), Bt11×MIR604 (eventcode: SYN-BTØ11-1×SYN-IR6Ø4-5, gene: pat, e.g. commercially available asAgrisure™ CB/LL/RW), BT11×MIR604×GA21 (event code:SYN-BTØ11-1×SYN-IR6Ø4-5×MON-ØØØ21-9, gene: pat, e.g. commerciallyavailable as Agrisure™ 3000GT), Bt176 (176) (event code: SYN-EV176-9,gene: bar, e.g. commercially available as NaturGard KnockOut™,Maximizer™), CBH-351 (event code: ACS-ZMØØ4-3, gene: bar, e.g.commercially available as Starlink™ Maize), DBT418 (event code:DKB-89614-9, gene: bar, e.g. commercially available as Bt Xtra™ Maize),MON89034×TC1507×MON88017×59122 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88017-3×DAS-59122-7, gene: pat, e.g.commercially available as Genuity® SmartStax™), MON89034×TC1507×NK603(event code: MON-89Ø34-3×DAS-Ø15Ø7-1×MON-ØØ6Ø3-6, gene: pat, e.g.commercially available as Power Core™), NK603×T25 (event code:MON-ØØ6Ø3-6×ACS-ZMØØ3-2, gene: pat, e.g. commercially available asRoundup Ready™ Liberty Link™ Maize), T14 (event code: ACS-ZMØØ2-1, gene:pat, e.g. commercially available as Liberty Link™ Maize), T25 (eventcode: ACS-ZMØØ3-2, gene: pat, e.g. commercially available as LibertyLink™ Maize), T25×MON810 (event code: ACS-ZMØØ3-2×MON-ØØ81Ø-6, gene:pat, e.g. commercially available as Liberty Link™ Yieldgard™ Maize),TC1507 (event code: DAS-Ø15Ø7-1, gene: pat, e.g. commercially availableas Herculex™ I, Herculex™ CB), TC1507×59122×MON810×MIR604×NK603 (eventcode: DAS-Ø15Ø7-1×DAS-59122-7×MON-ØØ81Ø-6×SYN-IR6Ø4-5×MON-ØØ6Ø3, gene:pat, e.g. commercially available asOptimum™ Intrasect Xtreme),TC1507×59122 (event code: DAS-Ø15Ø7-1×DAS-59122-7, gene: pat, e.g.commercially available as Herculex XTRA™), TC1507×59122×MON810×NK603(event code: DAS-Ø15Ø7-1×DAS-59122-7×MON-ØØ81Ø-6×MON-ØØ6Ø3-6, gene: pat,e.g. commercially available as Optimum™ Intrasect XTRA),TC1507×59122×NK603 (event code: DAS-Ø15Ø7-1×DAS-59122-7×MON-ØØ6Ø3-6,gene: pat, e.g. commercially available as Herculex XTRA™ RR),TC1507×MIR604×NK603 (event code: DAS-Ø15Ø7-1×SYN-IR6Ø4-5×MON-ØØ6Ø3-6,gene: pat, e.g. commercially available as Optimum™ TRIsect),TC1507×MON810×NK603 (event code: DAS-Ø15Ø7-1×MON-ØØ81Ø-6×MON-ØØ6Ø3-6,gene: pat, e.g. commercially available as Optimum™ Intrasect),TC1507×NK603 (event code: DAS-Ø15Ø7-1×MON-ØØ6Ø3-6, gene: pat, e.g.commercially available as Herculex™ I RR), 3272×Bt11 (event code:,SYN-E3272-5×SYN-BTØ11-1 gene: pat), 3272×Bt11×GA21 (event code:SYN-E3272-5×SYN-BTØ11-1×MON-ØØØ21-9, gene: pat), 3272×Bt11×MIR604 (eventcode: SYN-E3272-5×SYN-BTØ11-1×SYN-IR6Ø4-5, gene: pat),3272×BT11×MIR604×GA21 (event code:SYN-E3272-5×SYN-BTØ11-1×SYN-IR6Ø4-5×MON-ØØØ21-9, gene: pat), 33121(event code: DP-Ø33121-3, gene: pat), 4114 (event code: DP-ØØ4114-3,gene: pat), 59122×GA21 (event code: DAS-59122-7×MON-ØØØ21-9, gene: pat),59122×MIR604 (event code: DAS-59122-7×SYN-IR6Ø4-5, gene: pat),5307×MIR604×Bt11×TC1507×GA21×MIR162 (event code:, gene: pat),59122×MIR604×GA21 (event code: DAS-59122-7×SYN-IR6Ø4-5×MON-ØØØ21-9,gene: pat), 59122×MIR604×TC1507 (event code:DAS-59122-7×SYN-IR6Ø4-5×DAS-Ø15Ø7-1, gene: pat),59122×MIR604×TC1507×GA21 (event code:, gene: pat), (event code:DAS-59122-7×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat),59122×MON810 (event code: DAS-59122-7×MON-ØØ81Ø-6, gene: pat),59122×MON810×NK603 (event code: DAS-59122-7×MON-ØØ81Ø-6×MON-ØØ6Ø3-6,gene: pat), 59122×TC1507×GA21 (event code:DAS-59122-7×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat), 676 (event code:PH-ØØØ676-7, gene: pat), 678 (event code: PH-ØØØ678-9, gene: pat), 680(event code: PH-ØØØ68Ø-2, gene: pat), 98140×59122 (event code:DP-Ø9814Ø-6×DAS-59122-7, gene: pat), 98140×TC1507 (event code:DP-Ø9814Ø-6×DAS-Ø15Ø7-1, gene: pat), 98140×TC1507×59122 (event code:DP-Ø9814Ø-6×DAS-Ø15Ø7-1×DAS-59122-7, gene: pat), 59122×MON88017 (eventcode: DAS-59122-7×MON-88Ø17-3, gene: pat), Bt11×59122 (event code:SYN-BTØ11-1×DAS-59122-7, gene: pat), Bt11×59122×GA21 (event code:SYN-BTØ11-1×DAS-59122-7×MON-ØØØ21-9, gene: pat), Bt11×59122×MIR604(event code: SYN-BTØ11-1×DAS-59122-7×SYN-IR6Ø4-5, gene: pat),Bt11×59122×MIR604×GA21 (event code:SYN-BTØ11-1×DAS-59122-7×SYN-IR6Ø4-5×MON-ØØØ21-9, gene: pat),Bt11×59122×MIR604×TC1507 (event code: Bt11×59122×MIR604×TC1507, gene:pat), Bt11×59122×TC1507 (event code:SYN-BTØ11-1×DAS-59122-7×DAS-Ø15Ø7-1, gene: pat), Bt11×59122×TC1507×GA21(event code: SYN-BTØ11-1×DAS-59122-7×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene:pat), Bt11×MIR162×TC1507 (event code:SYN-BTØ11-1×SYN-IR162-4×DAS-Ø15Ø7-1, gene: pat), Bt11×MIR604×TC1507(event code: SYN-BTØ11-1×SYN-IR6Ø4-5×DAS-Ø15Ø7-1, gene: pat),Bt11×TC1507 (event code: SYN-BTØ11-1×DAS-Ø15Ø7-1, gene: pat),Bt11×TC1507×GA21 (event code: SYN-BTØ11-1×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene:pat), GA21×T25 (event code: MON-ØØØ21-9×ACS-ZMØØ3-2, gene: pat),MIR162×TC1507 (event code: SYN-IR162-4×DAS-Ø15Ø7-1, gene: pat),MIR162×TC1507×GA21 (event code: SYN-IR162-4×DAS-Ø15Ø7-1×MON-ØØØ21-9,gene: pat), MIR604×TC1507 (event code: SYN-IR6Ø4-5×DAS-Ø15Ø7-1, gene:pat), MON87427×MON89Ø34×TC15Ø7×MON88Ø17×59122 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-59122-7, gene: pat),MON89034×59122 (event code: MON-89Ø34-3×DAS-59122-7, gene: pat),MON89034×59122×MON88017 (event code:, gene: pat), MON89Ø34×TC1507 (eventcode: MON-89Ø34-3×DAS-59122-7×MON-88Ø17-3, gene: pat), (event code:MON-89Ø34-3×DAS-Ø15Ø7-1, gene: pat), MIR604×TC15Ø7 (event code:SYN-IR6Ø4-5×DAS-Ø15Ø7-1, gene: pat),MON87427×MON89Ø34×TC15Ø7×MON88Ø17×59122 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-59122-7, gene: pat),MON89034×59122 (event code: MON-89Ø34-3×DAS-59122-7, gene: pat),MON89034×59122×MON88017 (event code:, gene: pat), MON89034×TC1507 (eventcode: MON-89Ø34-3×DAS-59122-7×MON-88Ø17-3, gene: pat), (event code:MON-89Ø34-3×DAS-Ø15Ø7-1, gene: pat), DLL25 (B16) (event code:DKB-8979Ø-5, gene: bar), MIR604×TC1507 (event code:SYN-IR6Ø4-5×DAS-Ø15Ø7-1, gene: pat),MON87427×MON89Ø34×TC15Ø7×MON88Ø17×59122 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-59122-7, gene: pat),MON89034×59122 (event code: MON-89Ø34-3×DAS-59122-7, gene: pat),MON89034×59122×MON88017 (event code:MON-89Ø34-3×DAS-59122-7×MON-88Ø17-3, gene: pat), MON89034×TC1507 (eventcode: MON-89Ø34-3×DAS-Ø15Ø7-1, gene: pat), MON89034×TC1507×59122 (eventcode: MON-89Ø34-3×DAS-Ø15Ø7-1×DAS-59122-7, gene: pat),MON89034×TC1507×MON88017 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3, gene: pat),MON89034×TC1507×MON88017×59122×DAS40278 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-59122-7×DAS-4Ø278-9, gene: pat),MON89034×TC1507×MON88017×DAS40278 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-59122-7×DAS-4Ø278-9, gene: pat),MON89034×TC1507×NK603×DAS40278 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×MON-ØØ6Ø3-6×DAS-4Ø278-9, gene: pat),NK603×MON810×4114×MIR 604 (event code:MON-00603-6×MON-00810-6×DP004114-3×SYN-IR604-4, gene: pat),TC1507×MON810×MIR604×NK603 (event code:DAS-Ø15Ø7-1×MON-ØØ81Ø-6×SYN-IR6Ø4-5×MON-ØØ6Ø3-6, gene: pat),TC1507×59122×MON810 (event code: DAS-Ø15Ø7-1×DAS-59122-7×MON-ØØ81Ø-6,gene: pat), TC1507×59122×MON88017 (event code:DAS-Ø15Ø7-1×DAS-59122-7×MON-88Ø17-3, gene: pat), TC1507×GA21 (eventcode: DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat), TC1507×MON810 (event code:DAS-Ø15Ø7-1×MON-ØØ81Ø-6, gene: pat), TC1507×MON810×MIR162×NK603 (eventcode: DAS-Ø15Ø7-1×MON-ØØ81Ø-6×SYN-IR162-4×MON-ØØ6Ø3-6, gene: pat),3272×Bt11×MIR604×TC1507×5307×GA21 (event code:SYN-E3272-5×SYN-BTØ11-1×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9,gene: pat), TC1507×MIR162×NK603 (event code:DAS-Ø15Ø7-1×SYN-IR162-4×MON-ØØ6Ø3-6, gene: pat), TC1507×MON810×MIR162(event code: DAS-Ø15Ø7-1×MON-ØØ81Ø-6×SYN-IR162-4, gene: pat), MON87419(event code: MON87419-8, gene: pat), TC1507×MON88017 (event code:DAS-Ø15Ø7-1×MON-88Ø17-3, gene: pat), TC6275 (event code: DAS-Ø6275-8,gene: bar), MZHG0JG (event code: SYN-ØØØJG-2, gene: pat), MZIR098 (eventcode: SYN-ØØØ98-3, gene: pat), Bt11×MIR162×MON89034 (event code:SYN-BTØ11-1×SYN-IR162-4×MON-89Ø34-3, gene: pat) andBt11×MIR162×MON89Ø34×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×MON-89Ø34-3×MON-ØØØ21-9, gene: pat),59122×DAS40278 (event code: DAS-59122-7×DAS-4Ø278-9, gene: pat),59122×MON810×MIR604 (event code: DAS-59122-7×MON-ØØ81Ø-6×SYN-IR6Ø4-5,gene: pat), 59122×MON810×NK603×MIR604 (event code:DAS-59122-7×MON-ØØ81Ø-6×MON-ØØ6Ø3-6×SYN-IR6Ø4-5, gene: pat),59122×MON88017×DAS40278 (event code:DAS-59122-7×MON-88Ø17-3×DAS-4Ø278-9, gene: pat), 59122×NK603×MIR604(event code: DAS-59122-7×MON-ØØ6Ø3-6×SYN-IR6Ø4-5, gene: pat), Bt11×5307(event code: SYN-BTØ11-1×SYN-Ø53Ø7-1, gene: pat), Bt11×5307×GA21 (eventcode: SYN-BTØ11-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat), Bt11×MIR162×5307(event code: SYN-BTØ11-1×SYN-IR162-4×SYN-Ø53Ø7-1, gene: pat),Bt11×MIR162×5307×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),BT11×MIR162×MIR604×5307 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×SYN-Ø53Ø7-1, gene: pat),Bt11×MIR162×MIR604×5307×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),Bt11×MIR162×MIR604×MON89034×5307×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×MON-89Ø34-3×SYN-Ø53Ø7-1×MON-ØØØ21-9,gene: pat), BT11×MIR162×MIR604×TC1507 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1, gene: pat),BT11×MIR162×MIR604×TC1507×5307 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat),Bt11×MIR162×MIR604×TC1507×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat),Bt11×MIR162×TC1507×5307 (event code:SYN-BTØ11-1×SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat),BT11×MIR162×MIR604×TC1507×5307 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat),Bt11×MIR162×MIR604×TC1507×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat),Bt11×MIR162×TC1507×5307 (event code:SYN-BTØ11-1×SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat),Bt11×MIR162×TC1507×5307×GA21 (event code:SYN-BTØ11-1×SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),Bt11×MIR604×5307 (event code: SYN-BTØ11-1×SYN-IR6Ø4-5×SYN-Ø53Ø7-1, gene:pat), Bt11×MIR604×5307×GA21 (event code:SYN-BTØ11-1×SYN-IR6Ø4-5×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),Bt11×MIR604×TC1507×5307 (event code:SYN-BTØ11-1×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat),Bt11×MIR604×TC1507×GA21 (event code:SYN-BTØ11-1×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat),Bt11×MON89034 (or Bt11×MON89Ø34) (event code: SYN-BTØ11-1×MON-89Ø34-3,gene: pat), Bt11×MON89034×GA21 (event code:SYN-BTØ11-1×MON-8Ø34-3×MON-ØØØ21-9, gene: pat), Bt11×MON89Ø34×GA21(event code: SYN-BTØ11-1×MON-89Ø34-3×MON-ØØØ21-9, gene: pat),Bt11×TC1507×5307 (event code: SYN-BTØ11-1×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene:pat), Bt11×TC1507×5307×GA21 (event code:SYN-BTØ11-1×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),MIR162×MIR604×TC1507×5307 (event code:SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat),MIR162×MIR604×TC1507×5307×GA21 (event code:SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),MIR162×MIR604×TC1507×GA21 (event code:SYN-IR162-4×SYN-IR6Ø4-5×DAS-Ø15Ø7-1×MON-ØØØ21-9, gene: pat),MIR162×TC1507×5307 (event code: SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1,gene: pat), MIR162×TC1507×5307×GA21 (event code:SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),MIR604×TC1507×5307 (event code: SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1,gene: pat), MIR162×TC1507×5307 (event code:SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat), MIR162×TC1507×5307×GA21(event code: SYN-IR162-4×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene:pat), MIR604×TC1507×5307 (event code:SYN-IR6Ø4-5×DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat), MIR604×TC1507×5307'GA21(event code: SYN-IR6Ø4-5×TC1507×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),MIR604×TC1507×GA21 (event code: SYN-IR6Ø4-5×TC1507×MON-ØØØ21-9, gene:pat), MON87427×59122 (event code MON-87427-7×DAS-59122-7:, gene: pat),MON87427×MON89034×59122 (event code:MON-87427-7×MON-89Ø34-3×DAS-59122-7, gene: pat),MON87427×MON89034×MON88017×59122 (event code:MON-87427-7×MON-89Ø34-3×MON-88Ø17-3×59122, gene: pat),MON87427×MON89034×TC1507 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1, gene: pat),MON87427×MON89034×TC1507×59122 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×DAS-59122-7, gene: pat),MON87427×MON89034×TC1507×MON87411×59122 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×MON-87411-9×DAS-59122-7, gene: pat),MON87427×MON89034×TC1507×MON87411×59122×DAS40278 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×MON-87411-9×DAS-59122-7×DAS-4Ø278-9,gene: pat), MON87427×MON89034×TC1507×MON88017 (event code:MON-87427-7×MON-89Ø34-3×DAS-Ø15Ø7-1×MON-88Ø17-3, gene: pat),MON87427×TC1507 (event code: MON-87427-7×DAS-Ø15Ø7-1, gene: pat),MON87427×TC1507×59122 (event code: MON-87427-7×DAS-Ø15Ø7-1×DAS-59122-7,gene: pat), MON87427×TC1507×MON88017 (event code:MON-87427-7×DAS-Ø15Ø7-1×MON-88Ø17-3, gene: pat),MON87427×TC1507×MON88017×59122 (event code:MON-87427-7×DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-59122-7, gene: pat),MON89034×59122×DAS40278 (event code:MON-89Ø34-3×DAS-59122-7×DAS-4Ø278-9, gene: pat),MON89034×59122×MON88017×DAS40278 (event code:MON-89Ø34-3×DAS-59122-7×MON-88Ø17-3×DAS-4Ø278-9, gene: pat),MON89034×TC1507×59122×DAS40278 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×DAS-59122-7×DAS-4Ø278-9, gene: pat),MON89034×TC1507×DAS40278 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×DAS-4Ø278-9, gene: pat),MON89034×TC1507×NK603×MIR162 (event code:MON-89Ø34-3×DAS-Ø15Ø7-1×MON-ØØ6Ø3-6×SYN-IR162-4, gene: pat), TC1507×5307(event code: DAS-Ø15Ø7-1×SYN-Ø53Ø7-1, gene: pat), TC1507×5307×GA21(event code: DAS-Ø15Ø7-1×SYN-Ø53Ø7-1×MON-ØØØ21-9, gene: pat),TC1507×59122×DAS40278 (event code: DAS-Ø15Ø7-1×DAS-59122-7×DAS-4Ø278-9,gene: pat), TC1507×59122×MON810×MIR604 (event code:DAS-Ø15Ø7-1×DAS-59122-7×MON-ØØ81Ø-6×SYN-IR6Ø4-5, gene: pat),TC1507×59122×MON88017×DAS40278 (event code:DAS-Ø15Ø7-1×DAS-59122-7×MON-88Ø17-3×DAS-4Ø278-9, gene: pat),TC1507×59122×NK603×MIR604 (event code:, gene: pat)DAS-Ø15Ø7-1×DAS-59122-7×MON-ØØ6Ø3-6×SYN-IR6Ø4-5, TC1507×DAS40278 (eventcode: DAS-Ø15Ø7-1×DAS-4Ø278-9, gene: pat), TC1507×MON810×MIR604 (eventcode: DAS-Ø15Ø7-1×MON-ØØ81Ø-6×SYN-IR6Ø4-5, gene: pat),TC1507×MON810×NK603×MIR604 (event code:DAS-Ø15Ø7-1×MON-ØØ81Ø-6×MON-ØØ6Ø3-6×SYN-IR6Ø4-5, gene: pat),TC1507×MON88017×DAS40278 (event code:DAS-Ø15Ø7-1×MON-88Ø17-3×DAS-4Ø278-9, gene: pat) andTC1507×NK603×DAS40278 (event code: DAS-Ø15Ø7-1×MON-ØØ6Ø3-6×DAS-4Ø278-9,gene: pat).

In other aspects, corn plants of the invention include those plantswhich have been subjected to genetic modifications other thanglufosinate tolerance by breeding, mutagenesis or genetic engineering,e.g. have been rendered tolerant to applications of specific otherclasses of herbicides, such as PPO inhibitors (e. g. saflufenacil,trifludimoxazin), AHAS inhibitors; auxinic herbicides such as dicamba or2,4-D; bleaching herbicides such as hydroxyphenylpyruvate dioxygenase(HPPD) inhibitors (e. g. isoxaflutole, mesotrione, tembotrione,topramezone, bicyclopyrone) or phytoene desaturase (PDS) inhibitors;EPSPS inhibitors such as glyphosate; glutamine synthetase (GS)inhibitors such as glufosinate; lipid biosynthesis inhibitors such asacetyl CoA carboxylase (ACCase) inhibitors such as “dims” {e.g.,cycloxydim, sethoxydim, clethodim, or tepraloxydim), “fops” {e.g. ,clodinafop, diclofop, fluazifop, haloxyfop, or quizalofop), and “dens”(such as pinoxaden); or oxynil {i.e. bromoxynil or ioxynil) herbicidesas a result of conventional methods of breeding or genetic engineering,Thus, corn plants of the invention can be made resistant to multipleclasses of herbicides through multiple genetic modifications, such asfor example resistance to both glyphosate and dicamba; glyphosate, 2,4-Dand “fop” herbicides (e. g. Enlist® corn); glyphosate and glufosinate;glyphosate, dicamba and glufosinate; glyphosate and PPO inhibitors;glufosinate and PPO inhibitors; glyphosate, glufosinate and PPOinhibitors; glyphosate, dicamba and PPO inhibitors; glyphosate, 2,4-D,“fop” herbicides and PPO inhibitors; glyphosate, dicamba, glufosinateand PPO inhibitors; glyphosate, 2,4-D, “fop” herbicides, glufosinate andPPO inhibitors; or to one of the aforementioned corn plants that aretolerant to further classes of herbicides such as AHAS inhibitors orACCase inhibitors. These herbicide resistance technologies are, forexample, described in Pest Management Science (at volume, year, page):61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005,286; 64, 2008, 326; 64, 2008, 332; Weed Science 57, 2009, 108;Australian Journal of Agricultural Research 58, 2007, 708; Science 316,2007, 1185; and references quoted therein. In addition to these classesof inhibitors, corn plants of the invention may also be tolerant toherbicides having other modes of action, for example,chlorophyll/carotenoid pigment inhibitors, cell membrane disrupters,photosynthesis inhibitors, cell division inhibitors, root inhibitors,shoot inhibitors, and combinations thereof.

Such additional tolerance traits may be expressed, e.g.: as mutant orwildtype PPO proteins, as mutant AHASL proteins, mutant ACCase proteins,mutant EPSPS proteins, or mutant glutamine synthetase proteins; or asmutant native, inbred, or transgenic aryloxyalkanoate dioxygenase (AADor DHT), haloarylnitrilase (BXN), 2,2-dichloropropionic aciddehalogenase (DEH), glyphosate-N-acetyltransferase (GAT), glyphosatedecarboxylase (GDC), glyphosate oxidoreductase (GOX),glutathione-S-transferase (GST), phosphinothricin acetyltransferase (PATor bar), or CYP450s proteins having an herbicide-degrading activity.

Glufosinate tolerant corn plants hereof can also be stacked with othertraits including, but not limited to, pesticidal traits such as Bt Cryand other proteins having pesticidal activity toward coleopteran,lepidopteran, nematode, or other pests; nutrition or nutraceuticaltraits such as modified oil content or oil profile traits, high proteinor high amino acid concentration traits, and other trait types known inthe art.

In all treatments according to the methods of the present invention, theinventive mixtures can be applied in conventional manner by usingtechniques as skilled person is familiar with. Suitable techniquesinclude spraying, atomizing, dusting, spreading or watering. The type ofapplication depends on the intended purpose in a well known manner; inany case, they should ensure the finest possible distribution of theactive ingredients according to the invention.

In one embodiment, the inventive mixtures are applied to locus mainly byspraying, in particular foliar spraying of an aqueous dilution of theactive ingredients of the mixture. Application can be carried out bycustomary spraying techniques using, for example, water as carrier andspray liquor rates of from about 10 to 2000 l/ha or 50 to 1000 l/ha (forexample from 100 to 500 l/ha). Application of the inventive mixtures bythe low-volume and the ultra-low-volume method is possible, as is theirapplication in the form of microgranules.

The required application rate of the mixture of the pure activecompounds depends on the density of the undesired vegetation, on thedevelopment stage of the plants, on the climatic conditions of thelocation where the mixture is used and on the application method.

In general, the rate of application of L-glufosinate is usually from 50g/ha to 3000 g/ha and preferably in the range from 100 g/ha to 2000 g/haor from 200 g/ha to 1500 g/ha of active substance (a.i.), and the rateof application of the secod herbicida compound II is from 1 g/ha to 2000g/ha and preferably in the range from 5 g/ha to 1500 g/ha, morepreferably from 25 g/ha to 900 g/ha of active substance (a.i.).

The examples which follow illustrate the invention without imposing anylimitation.

BIOLOGICAL EXAMPLES

Synergism can be described as an interaction where the combined effectof two or more compounds is greater than the sum of the individualeffects of each of the compounds. The presence of a synergistic effectin terms of percent control, between two mixing partners (X and Y) canbe calculated using the Colby equation (Colby, S. R., 1967, CalculatingSynergistic and Antagonistic Responses in Herbicide Combinations, Weeds,15, 21-22):

$E = {X + Y - \frac{XY}{100}}$

When the observed combined control effect is greater than the expected(calculated) combined control effect (E), then the combined effect issynergistic.

The following tests demonstrate the control efficacy of compounds,mixtures or compositions of this invention on specific weeds. However,the weed control afforded by the compounds, mixtures or compositions isnot limited to these species. The analysis of synergism or antagonismbetween the mixtures or compositions was determined using Colby'sequation.

Test Method:

The culture containers used were plastic flowerpots containing loamysand with approximately 3.0% of humus as the substrate. The seeds of thetest plants were sown separately for each species and/or resistantbiotype. For the pre-emergence treatment, the active ingredients, whichhad been suspended or emulsified in water, were applied directly aftersowing by means of finely distributing nozzles. The containers wereirrigated gently to promote germination and growth and subsequentlycovered with transparent plastic hoods until the plants had rooted. Thiscover caused uniform germination of the test plants, unless this hadbeen impaired by the active ingredients. For the post-emergencetreatment, the test plants were first grown to a height of 3 to 15 cm,depending on the plant habit, and only then treated with the activeingredients which had been suspended or emulsified in water. For thispurpose, the test plants were either sown directly and grown in the samecontainers, or they were first grown separately as seedlings andtransplanted into the test containers a few days prior to treatment.Depending on the species, the plants were kept at 10-25° C. or 20-35°C., respectively. The test period extended to 20 days after treatment.During this time, the plants were tended, and their response to theindividual treatments was evaluated. The evaluation was carried out byusing a scale from 0 to 100. 100 means no emergence of the plants orcomplete destruction of at least the above-ground parts, and 0 means nodamage, or normal course of growth. Data shown are the mean of tworeplications.

Products:

L-Glufosinate: 5% EC formulation

Saflufenacil: 342 g/l SC formulation

Compound II-83: 5% EC formulation (Compound II-16: ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate)

Trifludimoxazin: 500 g/l SC formulation

Pyroxasulfone: 85% WG formulation

Pethoxamid: 5% EC formulation

2,4-D dimethylammonium salt: 500 g/l SL formulation (concentrationcalculated for 2,4-D acid)

Dicamba dimethylammonium salt: 480 g/l SL formulation (concentrationcalculated for dicamba acid)

Bicyclopyrone: 5% EC formulation

Dimethenamid-P: 720 g/l EC formulation

S-Metolachlor: 960 g/l EC formulation

Sulfentrazone: 480 g/l SC formulation

Weeds in the Study:

EPPO Code Scientific Name ABUTH Abutilon theophrasti ECHCG Echinochloacrus-galli AVEFA Avena fatua SETVI Setaria viridis COMBE Commelinabenghalensis KCHSC Kochia scoparia CHEAL Chenopodium album CYPIR Cyperusiria ERICA Erigeron Canadensis, Conyza canadensis

Example 1 Post Emergence Treatment with the Mixture of L-Glufosinatewith Saflufenacil

Herbicidal activity against Application rate in g ai/ha ECHCGL-Glufosinate Saflufenacil Found Calculated 400 — 65 — — 0.5 0 — 400 0.597 65 200 — 0 — — 0.5 0 — 200 0.5 35  0

Example 2 Post Emergence Treatment with the Mixture of L-Glufosinatewith Compound II-83 (ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate)

Herbicidal activity against Application rate in g ai/ha CYPIRL-Glufosinate Compound II-83 Found Calculated 200 — 0 — — 0.25 0 — 2000.25 35 0

Example 3 Post Emergence Treatment with the Mixture of L-Glufosinatewith Trifludimoxazin

Herbicidal activity against Application rate in g ai/ha ECHCGL-Glufosinate Trifludimoxazin Found Calculated 400 — 65 — — 0.25 10 —400 0.25 75 69 200 — 0 — — 0.25 10 — 200 0.25 33 10

Example 4 Post Emergence Treatment with the Mixture of L-Glufosinatewith Pyroxasulfone

Herbicidal activity against Application rate in g ai/ha ABUTHL-Glufosinate Pyroxasulfone Found Calculated 200 — 65 — — 50 70 — 200 50100 90 200 — 65 — — 25 40 — 200 25 100 79

Example 5 Post Emergence Treatment with the Mixture of L-Glufosinatewith Pethoxamid

Herbicidal activity against Application rate in g ai/ha ABUTH AVEFAL-Glufosinate Pethoxamid Found Calculated Found Calculated 150 — 55 — 0— — 100 0 — 0 — 150 100 98 55 40 0  75 — 0 — 0 — —  50 0 — 0 —  75  5035  0 5 0

Example 6 Post Emergence Treatment with the Mixture of L-Glufosinatewith 2,4-D dimethylammonium Salt

Application rate in g ai/ha 2,4-D as dimethyl- Herbicidal activityagainst ammonium AVEFA SETVI L-Glufosinate salt Found Calculated FoundCalculated 100 — 35 — 30 — — 140 0 — 0 — 100 140 65 35 65 30 100 — 35 —30 — —  70 0 — 0 — 100  70 40 35 65 30

Example 7 Post Emergence Treatment with the Mixture of L-Glufosinatewith Dicamba dimethylammonium Salt

Application rate in g ai/ha Dicamba as dimethyl- Herbicidal activityagainst ammonium SETVI L-Glufosinate salt Found Calculated 100 — 30 — —140  30 — 100 140  80 51 100 — 30 — — 70 0 — 100 70 65 30 100 — 30 — —35 0 — 100 35 60 30

Example 8 Post Emergence Treatment with the Mixture of L-Glufosinatewith Bicyclopyrone

Application rate in g ai/ha Herbicidal activity against Bicyclo- COMBEECHCG L-Glufosinate pyrone Found Calculated Found Calculated 100 — 0 — 0— — 2 10 — 0 — 100 2 30 10 55 0 100 — 0 — 0 — — 1 0 — 0 — 100 1 25  0 300

Example 9 Post Emergence Treatment with the Mixture of L-Glufosinatewith dimethenamid-P

Herbicidal activity against Application rate in g ai/ha KCHSCL-Glufosinate Dimethenamid-P Found Calculated 200 — 90 — — 1000 70 — 2001000 100 97 200 — 90 — —  500 0 — 200  500 100 90

Example 10 Post Emergence Treatment with the Mixture of L-Glufosinatewith S-metolachlor

Herbicidal activity against Application rate in g ai/ha CHEALL-Glufosinate S-Metolachlor Found Calculated 100 — 0 — — 1000 75 — 1001000 85 75 100 — 0 — —  500 20 — 100  500 85 20

Example 11 Post Emergence Treatment with the Mixture of L-Glufosinatewith Sulfentrazone

Herbicidal activity against Application rate in g ai/ha ERICAL-Glufosinate Sulfentrazone Found Calculated 75 — 90 — — 2.5  0 — 752.5  100 90 75 — 90 — — 1.25 0 — 75 1.25 100 90

1.-15. (canceled)
 16. A method for controlling undesirable vegetation inglufosinate tolerant corn, which method comprises applying to theundesirable vegetation or the locus thereof or applying to the soil orwater an herbicidal mixture comprising a) L-glufosinate and its salts,and b) a herbicidal compound II selected from the group consisting ofclethodim, cycloxydim, haloxyfop, haloxyfop-methyl, haloxyfop-P,haloxyfop-P-methyl, quizalofop, quizalofop-ethyl, quizalofop-tefuryl,quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, chlorimuron,chlorimuron-ethyl, foramsulfuron, halosulfuron, halosulfuron-methyl,iodosulfuron, iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron,rimsulfuron, thifensulfuron, thifensulfuron-methyl, tritosulfuron,imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr,imazapyr isopropylammonium, imazethapyr, imazethapyr ammonium,diclosulam, flumetsulam, florasulam, metosulam, thiencarbazone,thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil andits salts and esters, bentazone, bentazone-sodium, pyridate,carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, picolinafen, bicyclopyrone, clomazone,isoxaflutole, mesotrione, sulcotrione, tembotrione, tolpyralate,topramezone, fenquinotrione, glyphosate, glyphosate dimethylammmonium,glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metazachlor, metolachlor, S-metolachlor, pethoxamid,flufenacet, pyroxasulfone, 2,4-D and its salts and esters, clopyralidand its salts and esters, dicamba and its salts and esters, quinclorac,quinclorac dimethylammonium, quinmerac,diflufenzopyr,diflufenzopyr-sodium, cinmethylin, MCPA and its salts and esters, II-83:ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate(CAS 353292-31-6, S-3100), II-84:2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-aceticacid methyl ester (CAS 1970221-16-9), II-85:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide(CAS 2158276-22-1), II-86:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid ethyl ester (CAS 2158274-56-5), II-87:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide(CAS 2158274-53-2), II-88:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid ethyl ester (CAS 2158274-50-9), II-89: ethyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate(CAS 2230679-62-4); II-90:2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-aceticacid methyl ester (CAS 2158275-73-9), II-91:2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-aceticacid methyl ester (CAS 2158274-96-3), and II-92: methyl2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy]acetate,wherein L-glufosinate comprises more than 70% by weight of theL-enantiomer.
 17. The method of claim 16, wherein compound I in theherbicidal mixture is selected from the group consisting ofL-glufosinate-ammonium, L-glufosinate-sodium as L-glufosinate salts, andL-glufosinate as free acid.
 18. The method of claim 16, wherein compoundI in the herbicidal mixture is L-glufosinate-ammonium.
 19. The method ofclaim 16, wherein L-glufosinate in the herbicidal mixture comprises morethan 80% by weight of the L-enantiomer.
 20. The method of claim 16,wherein compound II in the herbicidal mixture is selected from the groupconsisting of clethodim, cycloxydim, haloxyfop, haloxyfop-methyl,haloxyfop-P, haloxyfop-P-methyl, quizalofop, quizalofop-ethyl,quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl,quizalofop-P-tefuryl, chlorimuron, chlorimuron-ethyl, foramsulfuron,halosulfuron, halosulfuron-methyl, iodosulfuron,iodosulfuron-methyl-sodium, nicosulfuron, prosulfuron, rimsulfuron,thifensulfuron, thifensulfuron-methyl, tritosulfuron, imazamox, imazamoxammonium, imazapic, imazapic ammonium, imazapyr, imazapyrisopropylammonium, imazethapyr, imazethapyr ammonium, diclosulam,flumetsulam, florasulam, metosulam, thiencarbazone,thiencarbazone-methyl, atrazine, simazine, terbuthylazin, bromoxynil andits salts and esters, bentazone, bentazone-sodium, pyridate,carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl,flumioxazin, fluthiacet, fluthiacet-methyl, saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, bicyclopyrone, clomazone, isoxaflutole,mesotrione, sulcotrione, tembotrione, tolpyralate, topramezone,fenquinotrione, glyphosate, glyphosate dimethylammmonium, glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metolachlor, S-metolachlor, pethoxamid, flufenacet,pyroxasulfone, 2,4-D and its salts and esters, clopyralid and its saltsand esters, dicamba and its salts and esters, diflufenzopyr,diflufenzopyr-sodium, MCPA and its salts and esters, compounds II-83,II-84, II-85, II-86, II-87, II-88, II-89, II-90, II-91 and II-92. 21.The method of claim 16, wherein the compound II in the herbicidalmixture is selected from the group of saflufenacil, sulfentrazone,tiafenacil, trifludimoxazin, and compounds II-83, II-84, II-85, II-86,II-87, II-89, II-90, II-91 and II-92.
 22. The method of claim 16,wherein the compound II in the herbicidal mixture is selected from thegroup of dimethenamid, dimethenamid-P, metolachlor, S-metolachlor,pethoxamid and pyroxasulfone.
 23. The method of claim 16, wherein thecompound II in the herbicidal mixture is selected from the group of2,4-D and its salts and esters, dicamba and its salts and esters,diflufenzopyr and diflufenzopyr sodium.
 24. The method of claim 16,wherein the weight ratio of compound Ito compound II is from 1000:1 to1:500.
 25. A pesticidal mixture, wherein the compounds I and II are asdefined in claim
 16. 26. A pesticidal composition, comprising a liquidor solid carrier and the mixture of claim
 25. 27. The method of claim 16wherein the glufosinate tolerant corn is a transgenic corn plant. 28.The method of claim 16, wherein compounds I and II of the mixture asdefined in claim 16 are applied simultaneously, that is jointly orseparately, or in succession.
 29. The method of claim 16, whereinL-glufosinate in the herbicidal mixture comprises more than 90% byweight of the L-enantiomer.
 30. The method of claim 16, whereinL-glufosinate in the herbicidal mixture comprises 95% by weight of theL-enantiomer.
 31. The method of claim 16, wherein compound II isselected from the group consisting of clethodim, cycloxydim, haloxyfop,haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, quizalofop,quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl,quizalofop-P-tefuryl, foramsulfuron, halosulfuron, halosulfuron-methyl,iodosulfuron, iodosulfuron-methyl-sodium, nicosulfuron, rimsulfuron,thifensulfuron, thifensulfuron-methyl, tritosulfuron, imazamox, imazamoxammonium, imazapic, imazapic ammonium imazapyr, imazapyrisopropylammonium, imazethapyr, imazethapyr ammonium, thiencarbazone,thiencarbazone-methyl, atrazine, terbuthylazin, bromoxynil and its saltsand esters, bentazone, bentazone-sodium, flumioxazin, saflufenacil,sulfentrazone, tiafenacil, trifludimoxazin, bicyclopyrone, isoxaflutole,mesotrione, sulcotrione, tembotrione, tolpyralate, topramezone,fenquinotrione, glyphosate, glyphosate dimethylammmonium,glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-trimesium(sulfosate), pendimethalin, acetochlor, butachlor, dimethenamid,dimethenamid-P, metolachlor, S-metolachlor, flufenacet, pyroxasulfone,2,4-D and its salts and esters, clopyralid and its salts and esters,dicamba and its salts and esters, diflufenzopyr, diflufenzopyr-sodium,MCPA and its salts and esters, compounds II-83, II-84, II-85, II-86,II-87, II-88, II-89, II-90, II-91 and II-92.
 32. The method of claim 16,wherein the compound II in the herbicidal mixture is selected from thegroup consisting of compounds II-83, II-84, II-85, II-86, II-87, II-88,II-89, II-90, II-91 and II-92; or selected from the group consisting ofbicyclopyrone, tolpyralate; or selected from the group consisting ofdimethenamid, dimethenamid-P, metolachlor, S-metolachlor, pethoxamid,pyroxasulfone; or selected from the group consisting of 2,4-D and itssalts and esters, dicamba and its salts and esters; or diflufenzopyr ordiflufenzopyr sodium.
 33. The method of claim 16, wherein the weightratio of compound I to compound II is from 500:1 to 1:250.